Innovative Castor Oil Derivative Synthesized through a Sustainable Approach Generating Reactive Cross-Linker from Secondary Products for Additive Manufacturing

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26310%2F26%3A0198520" target="_blank" >RIV/00216305:26310/26:0198520 - isvavai.cz</a>

Výsledek na webu

<a href="https://pubs.acs.org/doi/10.1021/acspolymersau.5c00055" target="_blank" >https://pubs.acs.org/doi/10.1021/acspolymersau.5c00055</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1021/acspolymersau.5c00055" target="_blank" >10.1021/acspolymersau.5c00055</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Innovative Castor Oil Derivative Synthesized through a Sustainable Approach Generating Reactive Cross-Linker from Secondary Products for Additive Manufacturing

Popis výsledku v původním jazyce

Additive manufacturing utilizes various reactive precursors to fabricate diverse products, including prototypes, functional components, and designer objects. This work presents a synthesis approach toward a novel biobased printable compound, 2-hydroxypropyl ricinoleate dimethacrylate (2-HPRDM). Our proposed strategy involves the castor oil transesterification process, producing 2-hydroxypropyl ricinoleate (2-HPR). We used high-performance liquid chromatography (HPLC) analysis to investigate the reaction progress at equimolar and excess reactant concentrations. This fatty acid ester was modified with methacrylic anhydride to form 2-HPRDM, releasing the secondary reaction product methacrylic acid (MA). This compound was used for the synthesis of propylene glycol dimethacrylate (PGDMA), which valorized all potential wastes generated during the 2-HPRDM production. This article presents the innovative vacuum-distillation esterification approach that generates PGDMA. All synthesized compounds were structurally characterized via NMR, ESI-MS, and FTIR analyses. The formed curable compounds were fabricated into testing specimens and a detailed prototype by an mSLA three-dimensional (3D) printer to confirm their usability. The 3D-printed object was used for the mechanical and thermomechanical characterization of the formulated curable resins via dynamic mechanical analysis (DMA), tensile, and flexural tests. The best-performing 2-HPRDM-based system contained 45 wt % of PGDMA and recorded a storage modulus of 750 MPa, a glass-transition temperature of 85.6 degrees C, a cross-linking density of 18.9 kmol/m3, a tensile strength of 16.1 +/- 2.4 MPa, and a flexural strength of 14.3 +/- 1.0 MPa.

Název v anglickém jazyce

Innovative Castor Oil Derivative Synthesized through a Sustainable Approach Generating Reactive Cross-Linker from Secondary Products for Additive Manufacturing

Popis výsledku anglicky

Additive manufacturing utilizes various reactive precursors to fabricate diverse products, including prototypes, functional components, and designer objects. This work presents a synthesis approach toward a novel biobased printable compound, 2-hydroxypropyl ricinoleate dimethacrylate (2-HPRDM). Our proposed strategy involves the castor oil transesterification process, producing 2-hydroxypropyl ricinoleate (2-HPR). We used high-performance liquid chromatography (HPLC) analysis to investigate the reaction progress at equimolar and excess reactant concentrations. This fatty acid ester was modified with methacrylic anhydride to form 2-HPRDM, releasing the secondary reaction product methacrylic acid (MA). This compound was used for the synthesis of propylene glycol dimethacrylate (PGDMA), which valorized all potential wastes generated during the 2-HPRDM production. This article presents the innovative vacuum-distillation esterification approach that generates PGDMA. All synthesized compounds were structurally characterized via NMR, ESI-MS, and FTIR analyses. The formed curable compounds were fabricated into testing specimens and a detailed prototype by an mSLA three-dimensional (3D) printer to confirm their usability. The 3D-printed object was used for the mechanical and thermomechanical characterization of the formulated curable resins via dynamic mechanical analysis (DMA), tensile, and flexural tests. The best-performing 2-HPRDM-based system contained 45 wt % of PGDMA and recorded a storage modulus of 750 MPa, a glass-transition temperature of 85.6 degrees C, a cross-linking density of 18.9 kmol/m3, a tensile strength of 16.1 +/- 2.4 MPa, and a flexural strength of 14.3 +/- 1.0 MPa.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

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OECD FORD obor

10404 - Polymer science

Projekt

—

Návaznosti

S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2025

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

ACS Polymers Au

ISSN

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e-ISSN

2694-2453

Svazek periodika

5

Číslo periodika v rámci svazku

5

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

12

Strana od-do

1-12

Kód UT WoS článku

001540457000001

EID výsledku v databázi Scopus

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