Towards the all organic Na-ion battery, using naturally occurring amino-and Hydroxy substituted Anthraquinones

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26310%2F26%3A0198524" target="_blank" >RIV/00216305:26310/26:0198524 - isvavai.cz</a>

Výsledek na webu

<a href="https://doi-org.ezproxy.lib.vutbr.cz/10.1016/j.electacta.2025.146346" target="_blank" >https://doi-org.ezproxy.lib.vutbr.cz/10.1016/j.electacta.2025.146346</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.electacta.2025.146346" target="_blank" >10.1016/j.electacta.2025.146346</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Towards the all organic Na-ion battery, using naturally occurring amino-and Hydroxy substituted Anthraquinones

Popis výsledku v původním jazyce

This study investigates the redox potential tunability of hydroxy- and amino-substituted anthraquinones (AQs) for their potential application in sodium-ion batteries (SIBs). As hydroxy-AQs are naturally occurring pigments and amino-AQs are commonly used in toners and inks, AQ and its derivatives have the potential to be a costeffective, abundant, and environmentally friendly cathode material for SIBs. A comparative analysis of ten distinct (di)hydroxy- and (di)amino-substituted AQs revealed substantial redox potential shifts of up to 700 mV in solution and 440 mV in a half-cell battery setup, depending on the substitution pattern. The most positive reduction potential in solution was observed for 1,5-dihydroxyanthraquinone (1,5OH-AQ), while 2,6-diaminoanthraquinone (2,6-NHS-AQ) exhibited the most negative value. OH-substituted AQs demonstrate anodic shifts, whereas NHS-substituted AQs induce cathodic shifts, which can be attributed to the combined effects of inductive (-I) and mesomeric (+M) influences, as well as intramolecular hydrogen bonding. To further understand the electronic and structural impact of these functional groups, ATR-FTIR analysis was conducted, revealing that the substitution position significantly affects the strength of the carbonyl bonds, leading to shifts in the C = O stretching vibration. Detailed electrochemical investigations, including cyclic voltammetry (CV) and galvanostatic charge/discharge cycling demonstrate that 1,5-OH-AQ and 2,6-NHS-AQ exhibit distinct and complementary redox properties. Their pronounced potential differences suggest a viable pathway for an all-organic AQ-based SIB, offering a promising alternative for sustainable energy storage.

Název v anglickém jazyce

Towards the all organic Na-ion battery, using naturally occurring amino-and Hydroxy substituted Anthraquinones

Popis výsledku anglicky

This study investigates the redox potential tunability of hydroxy- and amino-substituted anthraquinones (AQs) for their potential application in sodium-ion batteries (SIBs). As hydroxy-AQs are naturally occurring pigments and amino-AQs are commonly used in toners and inks, AQ and its derivatives have the potential to be a costeffective, abundant, and environmentally friendly cathode material for SIBs. A comparative analysis of ten distinct (di)hydroxy- and (di)amino-substituted AQs revealed substantial redox potential shifts of up to 700 mV in solution and 440 mV in a half-cell battery setup, depending on the substitution pattern. The most positive reduction potential in solution was observed for 1,5-dihydroxyanthraquinone (1,5OH-AQ), while 2,6-diaminoanthraquinone (2,6-NHS-AQ) exhibited the most negative value. OH-substituted AQs demonstrate anodic shifts, whereas NHS-substituted AQs induce cathodic shifts, which can be attributed to the combined effects of inductive (-I) and mesomeric (+M) influences, as well as intramolecular hydrogen bonding. To further understand the electronic and structural impact of these functional groups, ATR-FTIR analysis was conducted, revealing that the substitution position significantly affects the strength of the carbonyl bonds, leading to shifts in the C = O stretching vibration. Detailed electrochemical investigations, including cyclic voltammetry (CV) and galvanostatic charge/discharge cycling demonstrate that 1,5-OH-AQ and 2,6-NHS-AQ exhibit distinct and complementary redox properties. Their pronounced potential differences suggest a viable pathway for an all-organic AQ-based SIB, offering a promising alternative for sustainable energy storage.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

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OECD FORD obor

10401 - Organic chemistry

Projekt

<a href="/cs/project/8J24AT022" target="_blank" >8J24AT022: Inženýrství bočního řetězce adamantanu pro vysoce uspořádané organické polovodivé pigmenty a barviva</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2025

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

ELECTROCHIMICA ACTA

ISSN

0013-4686

e-ISSN

1873-3859

Svazek periodika

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Číslo periodika v rámci svazku

530

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

7

Strana od-do

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Kód UT WoS článku

001491365300005

EID výsledku v databázi Scopus

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