Thermal behaviour of yttrium aluminate glasses studied by DSC, high-temperature X-ray diffraction, SEM and SEM–EDS
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F17%3APU125756" target="_blank" >RIV/00216305:26620/17:PU125756 - isvavai.cz</a>
Výsledek na webu
<a href="http://dx.doi.org/10.1007/s10973-016-6078-2" target="_blank" >http://dx.doi.org/10.1007/s10973-016-6078-2</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s10973-016-6078-2" target="_blank" >10.1007/s10973-016-6078-2</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Thermal behaviour of yttrium aluminate glasses studied by DSC, high-temperature X-ray diffraction, SEM and SEM–EDS
Popis výsledku v původním jazyce
DSC, SEM–EDS, XRD and high-temperature XRD analysis was used to study thermal and crystallization behaviour of yttrium aluminate glasses prepared in the form of microspheres. The glasses YA-E (eutectic composition from the pseudo-binary system Al2O3–Y3Al5O12) and YA-G (a composition identical to the stoichiometric Y3Al5O12 (YAG) phase) were prepared by combination of the Pechini method with flame synthesis. The resulting microspheres were largely amorphous, but contained traces of yttrium–aluminium garnet as the main crystalline phase embedded in the yttrium aluminate glass matrix. Crystallization of the YAG phase was observed as the dominant exothermic process on DSC curves. From the DSC records, the basic thermal characteristics of the matrix glass, i.e. Tg (glass transition temperature), Tx (onset of crystallization peak temperature), Tf (temperature of the inflection point of the crystallization peak) and Tp (maximum of crystallization peak temperature), were determined. HT XRD experiments in the temperature interval 750–1200 C and isothermal HT XRD experiments at 932, 998 and 1200 C with 6-h holding time were also performed. Crystallization experiments at lower temperatures 932 C (YA-E) and 915 C (YA-G) were conducted to study phase development in a low-temperature region. Crystallization experiments at higher temperatures (1000, 1300 and 1500 C) with maximum holding time of 6 h were performed to study crystallization of a-Al2O3 in the eutectic system. The SEM and SEM–EDS examination of polished cross sections of crystallized microspheres revealed slow volume crystallization of the YAG phase in the AY-E glass. Eventually, polycrystalline microspheres with fine-grained microstructure were prepared after 6-h treatment at 1500 C.
Název v anglickém jazyce
Thermal behaviour of yttrium aluminate glasses studied by DSC, high-temperature X-ray diffraction, SEM and SEM–EDS
Popis výsledku anglicky
DSC, SEM–EDS, XRD and high-temperature XRD analysis was used to study thermal and crystallization behaviour of yttrium aluminate glasses prepared in the form of microspheres. The glasses YA-E (eutectic composition from the pseudo-binary system Al2O3–Y3Al5O12) and YA-G (a composition identical to the stoichiometric Y3Al5O12 (YAG) phase) were prepared by combination of the Pechini method with flame synthesis. The resulting microspheres were largely amorphous, but contained traces of yttrium–aluminium garnet as the main crystalline phase embedded in the yttrium aluminate glass matrix. Crystallization of the YAG phase was observed as the dominant exothermic process on DSC curves. From the DSC records, the basic thermal characteristics of the matrix glass, i.e. Tg (glass transition temperature), Tx (onset of crystallization peak temperature), Tf (temperature of the inflection point of the crystallization peak) and Tp (maximum of crystallization peak temperature), were determined. HT XRD experiments in the temperature interval 750–1200 C and isothermal HT XRD experiments at 932, 998 and 1200 C with 6-h holding time were also performed. Crystallization experiments at lower temperatures 932 C (YA-E) and 915 C (YA-G) were conducted to study phase development in a low-temperature region. Crystallization experiments at higher temperatures (1000, 1300 and 1500 C) with maximum holding time of 6 h were performed to study crystallization of a-Al2O3 in the eutectic system. The SEM and SEM–EDS examination of polished cross sections of crystallized microspheres revealed slow volume crystallization of the YAG phase in the AY-E glass. Eventually, polycrystalline microspheres with fine-grained microstructure were prepared after 6-h treatment at 1500 C.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
20504 - Ceramics
Návaznosti výsledku
Projekt
—
Návaznosti
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2017
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Journal of Thermal Analysis and Calorimetry
ISSN
1388-6150
e-ISSN
1588-2926
Svazek periodika
128
Číslo periodika v rámci svazku
3
Stát vydavatele periodika
HU - Maďarsko
Počet stran výsledku
9
Strana od-do
1407-1415
Kód UT WoS článku
000401349800017
EID výsledku v databázi Scopus
—