Corrosion resistance and surface microstructure of Mg3N2/SS thin films by plasma focus instrument

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F22%3APU144991" target="_blank" >RIV/00216305:26620/22:PU144991 - isvavai.cz</a>

Výsledek na webu

<a href="https://analyticalsciencejournals.onlinelibrary.wiley.com/doi/10.1002/jemt.24138" target="_blank" >https://analyticalsciencejournals.onlinelibrary.wiley.com/doi/10.1002/jemt.24138</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/jemt.24138" target="_blank" >10.1002/jemt.24138</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Corrosion resistance and surface microstructure of Mg3N2/SS thin films by plasma focus instrument

Popis výsledku v původním jazyce

Utilizing a plasma focus (PF) instrument, magnesium nitride (Mg3N2) thin films were synthesized on stainless steel substrates. Twenty five optimum focus shots at 8 cm distance from the anode tip were used to deposit the films at different angular positions regarded to the anode axis. Scanning electron microscopy (SEM), atomic force microscopy (AFM), and X-ray diffraction (XRD) analyses were performed to assess the surface morphology and structural characteristics of Mg3N2 films. Based on AFM images, these films were studied to understand the effect of angular position variation on their surfaces through morphological and fractal parameters. By increasing the angle, we verify that the grain size decreased from 130(0) nm to 75(5) nm and also the mean quadratic surface roughness of the films reduced in its average values from (28.97 +/- 3.24) nm to (23.10 +/- 1.34) nm. Power spectrum density analysis indicated that films become more self-affine at larger angles. Furthermore, the corrosion behavior of the films was investigated through a potentiodynamic polarization test in H2SO4 solution. It was found that the ion energy and flux, varying with the angular positions from the anode tip, directly affected the nanostructured roughness and surface morphology of the samples. The electrochemical studies of films show that the uncoated sample presented the lowest corrosion resistance. The highest corrosion resistance was obtained for the sample deposited with 25 optimum shots and at 0 degrees angular position reaching a reduction in the corrosion current density of almost 800 times compared to the pure stainless steel-304 substrate.

Název v anglickém jazyce

Corrosion resistance and surface microstructure of Mg3N2/SS thin films by plasma focus instrument

Popis výsledku anglicky

Utilizing a plasma focus (PF) instrument, magnesium nitride (Mg3N2) thin films were synthesized on stainless steel substrates. Twenty five optimum focus shots at 8 cm distance from the anode tip were used to deposit the films at different angular positions regarded to the anode axis. Scanning electron microscopy (SEM), atomic force microscopy (AFM), and X-ray diffraction (XRD) analyses were performed to assess the surface morphology and structural characteristics of Mg3N2 films. Based on AFM images, these films were studied to understand the effect of angular position variation on their surfaces through morphological and fractal parameters. By increasing the angle, we verify that the grain size decreased from 130(0) nm to 75(5) nm and also the mean quadratic surface roughness of the films reduced in its average values from (28.97 +/- 3.24) nm to (23.10 +/- 1.34) nm. Power spectrum density analysis indicated that films become more self-affine at larger angles. Furthermore, the corrosion behavior of the films was investigated through a potentiodynamic polarization test in H2SO4 solution. It was found that the ion energy and flux, varying with the angular positions from the anode tip, directly affected the nanostructured roughness and surface morphology of the samples. The electrochemical studies of films show that the uncoated sample presented the lowest corrosion resistance. The highest corrosion resistance was obtained for the sample deposited with 25 optimum shots and at 0 degrees angular position reaching a reduction in the corrosion current density of almost 800 times compared to the pure stainless steel-304 substrate.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

21002 - Nano-processes (applications on nano-scale); (biomaterials to be 2.9)

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2022

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

MICROSCOPY RESEARCH AND TECHNIQUE

ISSN

1059-910X

e-ISSN

1097-0029

Svazek periodika

85

Číslo periodika v rámci svazku

8

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

14

Strana od-do

2880-2893

Kód UT WoS článku

000789499300001

EID výsledku v databázi Scopus

2-s2.0-85129228717