A new light-element multi-principal-elements alloy AlMg2 TiZn and its potential for hydrogen storage
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F22%3APU147274" target="_blank" >RIV/00216305:26620/22:PU147274 - isvavai.cz</a>
Výsledek na webu
<a href="https://www.sciencedirect.com/science/article/pii/S0960148122012836?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0960148122012836?via%3Dihub</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.renene.2022.08.108" target="_blank" >10.1016/j.renene.2022.08.108</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
A new light-element multi-principal-elements alloy AlMg2 TiZn and its potential for hydrogen storage
Popis výsledku v původním jazyce
Hydrogen storage in a new-designed multi-principal-elements alloy (MPEA) AlMg2TiZn was studied. The chemical composition of the alloy ranks the alloy into the so-called light-elements family of MPEAs. The alloy was prepared by high energy ball milling and the measurements were carried out using Sieverts method in temperature interval 310?-370 ? under the hydrogen-gas pressure up to 25 bar. It was found that hydrogen absorption capacity was about 1.35-1.4 wt% H2. Activation energy of hydrogen desorption, Ea = 148 +/- 1 kJ/mol H2, was significantly lower than known value for pure Mg. Hydrogen absorption occurred in two steps, A1 and A2. The values of activation energy Ea = 175 +/- 12 kJ/mol H2 for rapid absorption A1 and Ea = 195 +/- 8 kJ/ mol H2 for subsequent slow absorption A2 were close to that for Mg. It was proposed that A1 was related to formation of alpha MgH2, the second one, A2, was related to formation of beta MgH2. Absolute value of hydride formation enthalpies, delta H = 75 +/- 3 kJ/mol H2 and delta H = 70 +/- 2 kJ/mol H2 obtained for A1 and A2, respectively, as well as value of delta H = 76 +/- 1 kJ/mol H2 for desorption were about the same as that for pure MgH2.
Název v anglickém jazyce
A new light-element multi-principal-elements alloy AlMg2 TiZn and its potential for hydrogen storage
Popis výsledku anglicky
Hydrogen storage in a new-designed multi-principal-elements alloy (MPEA) AlMg2TiZn was studied. The chemical composition of the alloy ranks the alloy into the so-called light-elements family of MPEAs. The alloy was prepared by high energy ball milling and the measurements were carried out using Sieverts method in temperature interval 310?-370 ? under the hydrogen-gas pressure up to 25 bar. It was found that hydrogen absorption capacity was about 1.35-1.4 wt% H2. Activation energy of hydrogen desorption, Ea = 148 +/- 1 kJ/mol H2, was significantly lower than known value for pure Mg. Hydrogen absorption occurred in two steps, A1 and A2. The values of activation energy Ea = 175 +/- 12 kJ/mol H2 for rapid absorption A1 and Ea = 195 +/- 8 kJ/ mol H2 for subsequent slow absorption A2 were close to that for Mg. It was proposed that A1 was related to formation of alpha MgH2, the second one, A2, was related to formation of beta MgH2. Absolute value of hydride formation enthalpies, delta H = 75 +/- 3 kJ/mol H2 and delta H = 70 +/- 2 kJ/mol H2 obtained for A1 and A2, respectively, as well as value of delta H = 76 +/- 1 kJ/mol H2 for desorption were about the same as that for pure MgH2.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
20703 - Mining and mineral processing
Návaznosti výsledku
Projekt
—
Návaznosti
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Ostatní
Rok uplatnění
2022
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
RENEWABLE ENERGY
ISSN
1879-0682
e-ISSN
—
Svazek periodika
198
Číslo periodika v rámci svazku
1
Stát vydavatele periodika
GB - Spojené království Velké Británie a Severního Irska
Počet stran výsledku
7
Strana od-do
1186-1192
Kód UT WoS článku
000865418600006
EID výsledku v databázi Scopus
2-s2.0-85137642025