Can electrodeposited Ti replace rolled Ti as substrate for the growth of anodic TiO2 nanotube layers?

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216305%3A26620%2F24%3APU151588" target="_blank" >RIV/00216305:26620/24:PU151588 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/00216275:25310/24:39921816

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S001346862400121X?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S001346862400121X?via%3Dihub</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.electacta.2024.143877" target="_blank" >10.1016/j.electacta.2024.143877</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Can electrodeposited Ti replace rolled Ti as substrate for the growth of anodic TiO2 nanotube layers?

Popis výsledku v původním jazyce

This study conducted a deep investigation of TiO2 nanotube (TNT) layers of two different thicknesses anodically grown on electrodeposited Ti films. The Ti films were grown from molten salts on Ni foils. The structure of the starting metals was compared by XRD (X -Ray Diffraction) and EBSD (Electron Backscatter Diffraction analyses), which showed a strong orientation towards the titanium (101) for the electrodeposited substrate, compared to the rather polycrystalline structure of the rolled Ti. The photoelectrochemical and electrochemical properties of 1 mu m and 5 mu m thick TNT layers anodically grown on these substrates were examined and compared with TNT layers of the same thickness. No significant morphological and compositional differences were found using SEM (Scanning Electron Microscopy) and XPS (X-ray Photoelectron Spectroscopy) between the TNT layers grown on the two substrates. However, higher photocurrent densities and ICPE values were observed for TNT layers grown on electrodeposited Ti. An in-depth investigation using Cyclic Voltammetry (CV) and Electrochemical Impedance Spectroscopy (EIS) analyses showed increased conductivity of the TNT layers produced on electrodeposited Ti compared to their counterparts. The carrier density (ND) for the TNT layers on electrodeposited Ti, calculated from Mott-Schottky measurements, showed a higher doping level than the TNT layers grown on Ti foils. This increase in ND results in more optimal photoelectrochemical performance of the TNT layers grown on electrodeposited Ti. All in all, the results presented herein pave the way for the use of electrodeposited Ti, with all its inherent benefits, and allow the further study of its promising properties in a wide range of applications.

Název v anglickém jazyce

Can electrodeposited Ti replace rolled Ti as substrate for the growth of anodic TiO2 nanotube layers?

Popis výsledku anglicky

This study conducted a deep investigation of TiO2 nanotube (TNT) layers of two different thicknesses anodically grown on electrodeposited Ti films. The Ti films were grown from molten salts on Ni foils. The structure of the starting metals was compared by XRD (X -Ray Diffraction) and EBSD (Electron Backscatter Diffraction analyses), which showed a strong orientation towards the titanium (101) for the electrodeposited substrate, compared to the rather polycrystalline structure of the rolled Ti. The photoelectrochemical and electrochemical properties of 1 mu m and 5 mu m thick TNT layers anodically grown on these substrates were examined and compared with TNT layers of the same thickness. No significant morphological and compositional differences were found using SEM (Scanning Electron Microscopy) and XPS (X-ray Photoelectron Spectroscopy) between the TNT layers grown on the two substrates. However, higher photocurrent densities and ICPE values were observed for TNT layers grown on electrodeposited Ti. An in-depth investigation using Cyclic Voltammetry (CV) and Electrochemical Impedance Spectroscopy (EIS) analyses showed increased conductivity of the TNT layers produced on electrodeposited Ti compared to their counterparts. The carrier density (ND) for the TNT layers on electrodeposited Ti, calculated from Mott-Schottky measurements, showed a higher doping level than the TNT layers grown on Ti foils. This increase in ND results in more optimal photoelectrochemical performance of the TNT layers grown on electrodeposited Ti. All in all, the results presented herein pave the way for the use of electrodeposited Ti, with all its inherent benefits, and allow the further study of its promising properties in a wide range of applications.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10400 - Chemical sciences

Projekt

—

Návaznosti

—

Rok uplatnění

2024

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

ELECTROCHIMICA ACTA

ISSN

0013-4686

e-ISSN

1873-3859

Svazek periodika

479

Číslo periodika v rámci svazku

143877

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

9

Strana od-do

„“-„“

Kód UT WoS článku

001174961700001

EID výsledku v databázi Scopus

2-s2.0-85183971751