Early hydration of C4AF with silica fume and its role on katoite composition

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F26232511%3A_____%2F24%3AN0000007" target="_blank" >RIV/26232511:_____/24:N0000007 - isvavai.cz</a>

Výsledek na webu

<a href="https://onlinelibrary-wiley-com.ezproxy.techlib.cz/journal/13652818" target="_blank" >https://onlinelibrary-wiley-com.ezproxy.techlib.cz/journal/13652818</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1111/jmi.13280" target="_blank" >10.1111/jmi.13280</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Early hydration of C4AF with silica fume and its role on katoite composition

Popis výsledku v původním jazyce

C4AF is considered the least reactive main clinker phase, but its reactivity may be affected by adding supplementary cementitious materials (SCMs). Pure C4AF was synthesised in a laboratory furnace, and the role of silica fume without gypsum on its early hydration properties was monitored. Burning was carried out in four stages to achieve 99% purity of C4AF. Heat flow development was monitored by isothermal calorimetry over 7 days of hydration at 20°C and 40°C. The role of silica fume on hydrogarnet phase katoite (Ca3Al2(SiO4)3 – x(OH)4x x = 1.5–3) formation during early hydration was studied. Rapid dissolution of C4AF, formation of metastable C-(A,F)-H and its conversion to C3(A, F)H6 was evidenced by isothermal calorimetry as a large exotherm. Changes in microstructure during early hydration were documented by SE micrographs, EDS point analyses, X-ray mapping and line scans by SEM-EDS. The phase composition was characterised by DTA-TGA and QXRD after 7 days of hydration. The katoite diffraction pattern is similar for the reference sample and sample with silica fume, but substitution in its structure can be revealed by X-ray microanalyses. The composition of katoite is variable due to the various extent of substitution of 4OH− by SiO44− due to silica fume.

Název v anglickém jazyce

Early hydration of C4AF with silica fume and its role on katoite composition

Popis výsledku anglicky

C4AF is considered the least reactive main clinker phase, but its reactivity may be affected by adding supplementary cementitious materials (SCMs). Pure C4AF was synthesised in a laboratory furnace, and the role of silica fume without gypsum on its early hydration properties was monitored. Burning was carried out in four stages to achieve 99% purity of C4AF. Heat flow development was monitored by isothermal calorimetry over 7 days of hydration at 20°C and 40°C. The role of silica fume on hydrogarnet phase katoite (Ca3Al2(SiO4)3 – x(OH)4x x = 1.5–3) formation during early hydration was studied. Rapid dissolution of C4AF, formation of metastable C-(A,F)-H and its conversion to C3(A, F)H6 was evidenced by isothermal calorimetry as a large exotherm. Changes in microstructure during early hydration were documented by SE micrographs, EDS point analyses, X-ray mapping and line scans by SEM-EDS. The phase composition was characterised by DTA-TGA and QXRD after 7 days of hydration. The katoite diffraction pattern is similar for the reference sample and sample with silica fume, but substitution in its structure can be revealed by X-ray microanalyses. The composition of katoite is variable due to the various extent of substitution of 4OH− by SiO44− due to silica fume.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

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OECD FORD obor

20100 - Civil engineering

Projekt

<a href="/cs/project/GA23-05122S" target="_blank" >GA23-05122S: Vliv kombinace tavidel, mineralizátorů a SCMs na vlastnosti nízkoenergetického slínku</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2024

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Microscopy

ISSN

0022-2720

e-ISSN

1365-2818

Svazek periodika

—

Číslo periodika v rámci svazku

02/2024

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

9

Strana od-do

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Kód UT WoS článku

001177648400001

EID výsledku v databázi Scopus

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