Formation of Phases in Reactively Sintered TiAl3 Alloy

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F26316919%3A_____%2F20%3AN0000012" target="_blank" >RIV/26316919:_____/20:N0000012 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/68378271:_____/20:00533533 RIV/60461373:22310/20:43921114

Výsledek na webu

<a href="https://www.mdpi.com/1420-3049/25/8/1912/htm" target="_blank" >https://www.mdpi.com/1420-3049/25/8/1912/htm</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/molecules25081912" target="_blank" >10.3390/molecules25081912</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Formation of Phases in Reactively Sintered TiAl3 Alloy

Popis výsledku v původním jazyce

This work highlights new results on the synthesis of the TiAl3 intermetallic phase using self-propagating high-temperature synthesis. This method is considered a promising sintering route for intermetallic compounds. It was found that the reactions proceed in two stages. Below the melting point of aluminum, the Ti2Al5 phase forms at 450 degrees C after long annealing times by a direct solid-state reaction between the aluminum and titanium, and is converted consequently to TiAl3. This is a completely new finding; until now, many authors have believed in the preferential formation of the TiAl3 phase. The second stage, the self-propagating strongly exothermic reaction, proceeds above the melting point of aluminum. It leads to the formation of the TiAl3 phase accompanied by Ti2Al5 and Ti3Al phases. The reaction mechanism was shown in the form of chemical equations, which were supported by calculating Gibbs energy. Reaction temperatures (T-onset, T-maximum, and T-offset) were determined after induction heating thanks to recording by an optical pyrometer. This finding provides completely new opportunities for the determination of activation energy at heating rates, in which common calorimeters are not able to detect a response or even measure. Now, the whole procedure will become accessible.

Název v anglickém jazyce

Formation of Phases in Reactively Sintered TiAl3 Alloy

Popis výsledku anglicky

This work highlights new results on the synthesis of the TiAl3 intermetallic phase using self-propagating high-temperature synthesis. This method is considered a promising sintering route for intermetallic compounds. It was found that the reactions proceed in two stages. Below the melting point of aluminum, the Ti2Al5 phase forms at 450 degrees C after long annealing times by a direct solid-state reaction between the aluminum and titanium, and is converted consequently to TiAl3. This is a completely new finding; until now, many authors have believed in the preferential formation of the TiAl3 phase. The second stage, the self-propagating strongly exothermic reaction, proceeds above the melting point of aluminum. It leads to the formation of the TiAl3 phase accompanied by Ti2Al5 and Ti3Al phases. The reaction mechanism was shown in the form of chemical equations, which were supported by calculating Gibbs energy. Reaction temperatures (T-onset, T-maximum, and T-offset) were determined after induction heating thanks to recording by an optical pyrometer. This finding provides completely new opportunities for the determination of activation energy at heating rates, in which common calorimeters are not able to detect a response or even measure. Now, the whole procedure will become accessible.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20501 - Materials engineering

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2020

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

MOLECULES

ISSN

1420-3049

e-ISSN

1420-3049

Svazek periodika

25

Číslo periodika v rámci svazku

8

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

13

Strana od-do

nestránkováno

Kód UT WoS článku

000534617500070

EID výsledku v databázi Scopus

2-s2.0-85083798339