Synthesis, structure and magnetic properties of Sm1.2Ho0.8Fe17Нx (x = 0; 4.4)

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F26722445%3A_____%2F21%3AN0000067" target="_blank" >RIV/26722445:_____/21:N0000067 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S1002072120303665" target="_blank" >https://www.sciencedirect.com/science/article/pii/S1002072120303665</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jre.2020.08.010" target="_blank" >10.1016/j.jre.2020.08.010</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Synthesis, structure and magnetic properties of Sm1.2Ho0.8Fe17Нx (x = 0; 4.4)

Popis výsledku v původním jazyce

Intermetallic compounds based on rare-earth metals and iron are by far the most promising materials for permanent magnets. In this work, the multicomponent compound Sm1.2Ho0.8Fe17 was prepared by induction melting. The hydride Sm1.2Ho0.8Fe17H4.4 with a high hydrogen content was obtained by direct hydrogenation of the intermetallic compound. The rhombohedral Th2Zn17-type of structure (space group ) is inherent to parent compound and hydride as well. The effect of hydrogenation on the magnetic properties of Sm1.2Ho0.8Fe17 was investigated. Curie temperature of the hydride Sm1.2Ho0.8-Fe17H4.4 is higher than that of parent compound by ΔTC = 138 K. The hydrogen embedded in Sm1.2Но0.8Fe17 crystal lattice increases the saturation magnetization (σS) at T = 300 K, but does not significantly affect σS at Т = 4.2 K. The ferrimagnetic structure is retained in magnetic fields up to 58 T in the parent compound, while, in the hydride, there is a spin-reorientation phase transition observed at 55 T. It is found that the parameter of the intersublattice exchange interaction decreases significantly in the hydride Sm1.2Ho0.8Fe17H4.4 (and in the nitride Sm1.2Ho0.8Fe17N2.4) which is associated with boosting of the unit-cell volume and distances between magnetic ions.

Název v anglickém jazyce

Synthesis, structure and magnetic properties of Sm1.2Ho0.8Fe17Нx (x = 0; 4.4)

Popis výsledku anglicky

Intermetallic compounds based on rare-earth metals and iron are by far the most promising materials for permanent magnets. In this work, the multicomponent compound Sm1.2Ho0.8Fe17 was prepared by induction melting. The hydride Sm1.2Ho0.8Fe17H4.4 with a high hydrogen content was obtained by direct hydrogenation of the intermetallic compound. The rhombohedral Th2Zn17-type of structure (space group ) is inherent to parent compound and hydride as well. The effect of hydrogenation on the magnetic properties of Sm1.2Ho0.8Fe17 was investigated. Curie temperature of the hydride Sm1.2Ho0.8-Fe17H4.4 is higher than that of parent compound by ΔTC = 138 K. The hydrogen embedded in Sm1.2Но0.8Fe17 crystal lattice increases the saturation magnetization (σS) at T = 300 K, but does not significantly affect σS at Т = 4.2 K. The ferrimagnetic structure is retained in magnetic fields up to 58 T in the parent compound, while, in the hydride, there is a spin-reorientation phase transition observed at 55 T. It is found that the parameter of the intersublattice exchange interaction decreases significantly in the hydride Sm1.2Ho0.8Fe17H4.4 (and in the nitride Sm1.2Ho0.8Fe17N2.4) which is associated with boosting of the unit-cell volume and distances between magnetic ions.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10402 - Inorganic and nuclear chemistry

Projekt

<a href="/cs/project/LQ1603" target="_blank" >LQ1603: Výzkum pro SUSEN</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2021

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Rare Earths

ISSN

1002-0721

e-ISSN

—

Svazek periodika

39

Číslo periodika v rámci svazku

9

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

6

Strana od-do

1089-1094

Kód UT WoS článku

000679416200010

EID výsledku v databázi Scopus

2-s2.0-85097235847