Tetramethyl(perfluoroalkyl)cyclopentadienyl rhodium(I) complexes with ethylene or diene ligands. Crystal structure of [(?5-C5Me4C6F13)Rh(CO)2]
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F44555601%3A13440%2F10%3A00005539" target="_blank" >RIV/44555601:13440/10:00005539 - isvavai.cz</a>
Výsledek na webu
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DOI - Digital Object Identifier
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Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Tetramethyl(perfluoroalkyl)cyclopentadienyl rhodium(I) complexes with ethylene or diene ligands. Crystal structure of [(?5-C5Me4C6F13)Rh(CO)2]
Popis výsledku v původním jazyce
Tetramethyl(perfluoroalkyl)cyclopentadienyl rhodium(I) complexes with ethylene or diene (norbornadiene, cycloocta-1,5-diene, 2,3-dimethylbuta-1,3-diene, cyclohexa-1,3-diene) ligands were obtained by reduction of tetramethyl(perfluoroalkyl)rhodium(III) dichloro dimers by zinc in THF or by propan-2-ol/sodium carbonate in the presence of the ligands. Reduction in the presence of cycloocta-1,3-diene gave a different product, an ?3-cyclooctenyl complex, which was not reduced further. During the reduction inthe presence of ethylene, a new tetramethyl(perfluoroalkyl)-?4-cyclopentadiene complex was observed by NMR. This compound, formed by hydrogen transfer from the metal to the ligand, is probably in an equilibrium with the parent hydridocyclopentadienyl complex. Crystal and molecular structure of dicarbonyltetramethyl(perfluorohexyl)cyclopentadienylrhodium(I) complex was determined by X-ray diffraction. The structure shows a moderate ring slippage of the rhodium atom which was not observed
Název v anglickém jazyce
Tetramethyl(perfluoroalkyl)cyclopentadienyl rhodium(I) complexes with ethylene or diene ligands. Crystal structure of [(?5-C5Me4C6F13)Rh(CO)2]
Popis výsledku anglicky
Tetramethyl(perfluoroalkyl)cyclopentadienyl rhodium(I) complexes with ethylene or diene (norbornadiene, cycloocta-1,5-diene, 2,3-dimethylbuta-1,3-diene, cyclohexa-1,3-diene) ligands were obtained by reduction of tetramethyl(perfluoroalkyl)rhodium(III) dichloro dimers by zinc in THF or by propan-2-ol/sodium carbonate in the presence of the ligands. Reduction in the presence of cycloocta-1,3-diene gave a different product, an ?3-cyclooctenyl complex, which was not reduced further. During the reduction inthe presence of ethylene, a new tetramethyl(perfluoroalkyl)-?4-cyclopentadiene complex was observed by NMR. This compound, formed by hydrogen transfer from the metal to the ligand, is probably in an equilibrium with the parent hydridocyclopentadienyl complex. Crystal and molecular structure of dicarbonyltetramethyl(perfluorohexyl)cyclopentadienylrhodium(I) complex was determined by X-ray diffraction. The structure shows a moderate ring slippage of the rhodium atom which was not observed
Klasifikace
Druh
J<sub>x</sub> - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
CEP obor
CC - Organická chemie
OECD FORD obor
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Návaznosti výsledku
Projekt
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Návaznosti
S - Specificky vyzkum na vysokych skolach
Ostatní
Rok uplatnění
2010
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Journal of Organometallic Chemistry
ISSN
0022-328X
e-ISSN
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Svazek periodika
695
Číslo periodika v rámci svazku
3
Stát vydavatele periodika
CH - Švýcarská konfederace
Počet stran výsledku
7
Strana od-do
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Kód UT WoS článku
000273782000010
EID výsledku v databázi Scopus
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