Epoxidation of methyl esters from waste vegetable oil by heterogeneous catalysts WO3/Al2O3

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F44555601%3A13440%2F24%3A43898520" target="_blank" >RIV/44555601:13440/24:43898520 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S2468823124007016?dgcid=coauthor" target="_blank" >https://www.sciencedirect.com/science/article/pii/S2468823124007016?dgcid=coauthor</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.mcat.2024.114519" target="_blank" >10.1016/j.mcat.2024.114519</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Epoxidation of methyl esters from waste vegetable oil by heterogeneous catalysts WO3/Al2O3

Popis výsledku v původním jazyce

The paper describes the catalytic epoxidation of methyl esters of higher fatty acids prepared from waste vegetable oils as a renewable raw material (the second important product is glycerol). Bio-epoxides as &quot;green products&quot; can be used instead of epoxides from crude oil in many applications such as bio-lubricants, biopolymers, polycarbonates, etc. The epoxidation was catalysed by ?-alumina impregnated with tungsten (5?15 wt.%) under different reaction conditions such as the type and amount of solvent (acetonitrile, ethyl acetate and tert?butanol) and amount of catalysts (0 to 75 wt.% to ester), molar ratio to ester (from 1 to 6) and reaction time (0?24 h). Characterization of tested catalysts was carried out by various analytical methods such as XRF, XRD, Raman spectroscopy, TPD-NH3, N2 physisorption, Hg-porozimetry, SEM-EDX. Moreover, the ternary plot for each solvent was determined to find the homogeneous region since ester and hydrogen peroxide are immiscible liquids. Finally, according to statistical evaluationed, it was found that methyl ester conversion increases with increasing number of Wdouble bondO bonds.

Název v anglickém jazyce

Epoxidation of methyl esters from waste vegetable oil by heterogeneous catalysts WO3/Al2O3

Popis výsledku anglicky

The paper describes the catalytic epoxidation of methyl esters of higher fatty acids prepared from waste vegetable oils as a renewable raw material (the second important product is glycerol). Bio-epoxides as &quot;green products&quot; can be used instead of epoxides from crude oil in many applications such as bio-lubricants, biopolymers, polycarbonates, etc. The epoxidation was catalysed by ?-alumina impregnated with tungsten (5?15 wt.%) under different reaction conditions such as the type and amount of solvent (acetonitrile, ethyl acetate and tert?butanol) and amount of catalysts (0 to 75 wt.% to ester), molar ratio to ester (from 1 to 6) and reaction time (0?24 h). Characterization of tested catalysts was carried out by various analytical methods such as XRF, XRD, Raman spectroscopy, TPD-NH3, N2 physisorption, Hg-porozimetry, SEM-EDX. Moreover, the ternary plot for each solvent was determined to find the homogeneous region since ester and hydrogen peroxide are immiscible liquids. Finally, according to statistical evaluationed, it was found that methyl ester conversion increases with increasing number of Wdouble bondO bonds.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10401 - Organic chemistry

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2024

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Molecular Catalysis

ISSN

2468-8274

e-ISSN

2468-8231

Svazek periodika

2024

Číslo periodika v rámci svazku

569

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

10

Strana od-do

"nestrankovano"

Kód UT WoS článku

001309576300001

EID výsledku v databázi Scopus

2-s2.0-85203005539