Kinetics of processes modeling corrosion of glass fibers mixed into concrete

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F46356088%3A_____%2F17%3AN0000029" target="_blank" >RIV/46356088:_____/17:N0000029 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/60461373:22310/17:43913967

Výsledek na webu

<a href="http://dx.doi.org/10.13168/cs.2017.0012" target="_blank" >http://dx.doi.org/10.13168/cs.2017.0012</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.13168/cs.2017.0012" target="_blank" >10.13168/cs.2017.0012</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Kinetics of processes modeling corrosion of glass fibers mixed into concrete

Popis výsledku v původním jazyce

The presented work involved model corrosion tests of silicazirconia glass fibers with two different types of lubrication (Anti-Crack HD with dispersible lubrication and Anti-Crack HP with non-dispersible lubrication). Also the corrosion tests of fibers with lubrication removed by firing was studied. All types of fibers were leached in alkaline solutions (Ca(OH)2 with pH 12.7, KOH with pH 12.7 and 14) at temperature of 80°C for 7 - 42 days. Changes in corrosion solutions composition and in glass surface were measured and characterized (AAS, ICP-OES and SEM-EDS, XRF, XRD resp.). The leaching results were similar for both types of fibers with or without lubrication. After leaching in the Ca(OH) 2 (pH 12.7), the fibers were covered with calcium precipitates. On fibers with lubrication the precipitate contained mainly crystalline calcium carbonate and calcium hydroxide, while on fibers with removed lubrication the precipitate also contained silicate. After the calciumcontaining precipitates were removed with an acid solution, pitting corrosion was visible on fibers with lubrication while fibers without lubrication were covered with a corrosion layer without a significant change in the surface composition. The fibers practically did not dissolve in that environment. In KOH (pH 12.7) the fibers slightly dissolved but without visible precipitates, the composition of all types of fibers did not substantially changed In KOH (pH 14) the fibers dissolved more significantly. On the surface of the fibers a ZrO2 and silica containing corrosion layer was formed. The time dependences of dissolved glass components indicates the incongruent dissolution of the fibers with selective leaching of sodium ions or congruent dissolution followed by precipitation of SiO2, or SiO2 with calcium ions from the solution. It is likely that both the created precipitates (calcium or calcium-silica) and the developed corrosion layers (silica - zirconia) may operate as a barrier which slows down further corrosion of glass fibers.

Název v anglickém jazyce

Kinetics of processes modeling corrosion of glass fibers mixed into concrete

Popis výsledku anglicky

The presented work involved model corrosion tests of silicazirconia glass fibers with two different types of lubrication (Anti-Crack HD with dispersible lubrication and Anti-Crack HP with non-dispersible lubrication). Also the corrosion tests of fibers with lubrication removed by firing was studied. All types of fibers were leached in alkaline solutions (Ca(OH)2 with pH 12.7, KOH with pH 12.7 and 14) at temperature of 80°C for 7 - 42 days. Changes in corrosion solutions composition and in glass surface were measured and characterized (AAS, ICP-OES and SEM-EDS, XRF, XRD resp.). The leaching results were similar for both types of fibers with or without lubrication. After leaching in the Ca(OH) 2 (pH 12.7), the fibers were covered with calcium precipitates. On fibers with lubrication the precipitate contained mainly crystalline calcium carbonate and calcium hydroxide, while on fibers with removed lubrication the precipitate also contained silicate. After the calciumcontaining precipitates were removed with an acid solution, pitting corrosion was visible on fibers with lubrication while fibers without lubrication were covered with a corrosion layer without a significant change in the surface composition. The fibers practically did not dissolve in that environment. In KOH (pH 12.7) the fibers slightly dissolved but without visible precipitates, the composition of all types of fibers did not substantially changed In KOH (pH 14) the fibers dissolved more significantly. On the surface of the fibers a ZrO2 and silica containing corrosion layer was formed. The time dependences of dissolved glass components indicates the incongruent dissolution of the fibers with selective leaching of sodium ions or congruent dissolution followed by precipitation of SiO2, or SiO2 with calcium ions from the solution. It is likely that both the created precipitates (calcium or calcium-silica) and the developed corrosion layers (silica - zirconia) may operate as a barrier which slows down further corrosion of glass fibers.

Druh

J_SC - Článek v periodiku v databázi SCOPUS

CEP obor

—

OECD FORD obor

20401 - Chemical engineering (plants, products)

Projekt

<a href="/cs/project/GA14-20856S" target="_blank" >GA14-20856S: Kinetika korozních dějů a transportu korozních médií v ultra-vysokopevnostních betonech (UHPC)</a><br>

Návaznosti

N - Vyzkumna aktivita podporovana z neverejnych zdroju

Rok uplatnění

2017

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Ceramics - Silikaty

ISSN

0862-5468

e-ISSN

—

Svazek periodika

61

Číslo periodika v rámci svazku

2

Stát vydavatele periodika

CZ - Česká republika

Počet stran výsledku

9

Strana od-do

163-171

Kód UT WoS článku

—

EID výsledku v databázi Scopus

2-s2.0-85018514791