Molecular-Level Speciation of Eu(III) Adsorbed on a Migmatized Gneiss As Determined Using μTRLFS
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F46356088%3A_____%2F21%3AN0000012" target="_blank" >RIV/46356088:_____/21:N0000012 - isvavai.cz</a>
Výsledek na webu
<a href="https://pubs.acs.org/doi/10.1021/acs.est.0c07998" target="_blank" >https://pubs.acs.org/doi/10.1021/acs.est.0c07998</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.est.0c07998" target="_blank" >10.1021/acs.est.0c07998</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Molecular-Level Speciation of Eu(III) Adsorbed on a Migmatized Gneiss As Determined Using μTRLFS
Popis výsledku v původním jazyce
The interaction of Eu(III) with thin sections of migmatized gneiss from the Bukov Underground Research Facility (URF), Czech Republic, was characterized by microfocus time-resolved laser-induced luminescence spectroscopy (μTRLFS) with a spatial resolution of ∼20 μm, well below typical grain sizes of the material. By this approach, sorption processes can be characterized on the molecular level while maintaining the relationship of the speciation with mineralogy and topography. The sample mineralogy was characterized by powder X-ray diffraction and Raman microscopy, and the sorption was independently quantified by autoradiography using 152Eu. Representative μTRLFS studies over large areas of multiple mm2 reveal that sorption on the heterogeneous material is not dominated by any of the typical major constituent minerals (quartz, feldspar, and mica). Instead, minor phases such as chlorite and prehnite control the Eu(III) distribution, despite their low contribution to the overall composition of the material, as well as common but less studied phases like Mg–hornblende. In particular, prehnite shows high a sorption uptake as well as strong binding of Eu to the mineral surface. Sorption on prehnite and hornblende happens at the expense of feldspar, which showed the highest sorption uptake in a previous spatially resolved study on granitic rock. Similarly, sorption on quartz is reduced, even though only low quantities of strongly bound Eu(III) were found here previously. Our results illustrate how competition of mineral surfaces for adsorbing cations drives the metal distribution in heterogeneous systems.
Název v anglickém jazyce
Molecular-Level Speciation of Eu(III) Adsorbed on a Migmatized Gneiss As Determined Using μTRLFS
Popis výsledku anglicky
The interaction of Eu(III) with thin sections of migmatized gneiss from the Bukov Underground Research Facility (URF), Czech Republic, was characterized by microfocus time-resolved laser-induced luminescence spectroscopy (μTRLFS) with a spatial resolution of ∼20 μm, well below typical grain sizes of the material. By this approach, sorption processes can be characterized on the molecular level while maintaining the relationship of the speciation with mineralogy and topography. The sample mineralogy was characterized by powder X-ray diffraction and Raman microscopy, and the sorption was independently quantified by autoradiography using 152Eu. Representative μTRLFS studies over large areas of multiple mm2 reveal that sorption on the heterogeneous material is not dominated by any of the typical major constituent minerals (quartz, feldspar, and mica). Instead, minor phases such as chlorite and prehnite control the Eu(III) distribution, despite their low contribution to the overall composition of the material, as well as common but less studied phases like Mg–hornblende. In particular, prehnite shows high a sorption uptake as well as strong binding of Eu to the mineral surface. Sorption on prehnite and hornblende happens at the expense of feldspar, which showed the highest sorption uptake in a previous spatially resolved study on granitic rock. Similarly, sorption on quartz is reduced, even though only low quantities of strongly bound Eu(III) were found here previously. Our results illustrate how competition of mineral surfaces for adsorbing cations drives the metal distribution in heterogeneous systems.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
20700 - Environmental engineering
Návaznosti výsledku
Projekt
<a href="/cs/project/TH02030543" target="_blank" >TH02030543: Vývoj nástrojů pro studium transportu kontaminantů v puklinovém prostředí</a><br>
Návaznosti
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Ostatní
Rok uplatnění
2021
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Environmental Science and Technology
ISSN
0013-936X
e-ISSN
1520-5851
Svazek periodika
55
Číslo periodika v rámci svazku
8
Stát vydavatele periodika
US - Spojené státy americké
Počet stran výsledku
9
Strana od-do
4871-4879
Kód UT WoS článku
000643546400067
EID výsledku v databázi Scopus
2-s2.0-85103444671