Effect of Waste Metal and Chamotte Fillers on the Thermal and Mechanical Properties of Geopolymer Composites for Energy Storage Applications

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F46747885%3A24210%2F25%3A00014026" target="_blank" >RIV/46747885:24210/25:00014026 - isvavai.cz</a>

Výsledek na webu

<a href="https://doi.org/10.3390/ma18163853" target="_blank" >https://doi.org/10.3390/ma18163853</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/ma18163853" target="_blank" >10.3390/ma18163853</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Effect of Waste Metal and Chamotte Fillers on the Thermal and Mechanical Properties of Geopolymer Composites for Energy Storage Applications

Popis výsledku v původním jazyce

This study investigates the effects of varying filler content on the thermal and mechanical performance of metakaolinite-based geopolymer composites designed for thermal energy storage applications. The composites were formulated using a geopolymer binder, combined with a thermally stable filler (ground chamotte) and a thermal energy storage filler (waste steel chips) in different proportions. Chamotte content within the binder matrix (binder + chamotte) ranged from 20 to 40 wt.%, while steel chip content varied from 0 to 40 wt.% of the total composite mass. The thermal properties of the composites were evaluated at room temperature and compared with conventional reference materials, including Ultraboard, chamotte brick, and magnetite brick. Mechanical performance, specifically flexural and compressive strength, was evaluated at room temperature and after exposure to elevated temperatures (800 and 1100 °C), followed by two cooling regimes, slow furnace cooling and rapid water quenching. Microstructural characterization via optical microscopy was used to examine filler dispersion and matrix–filler interactions. The results showed that the thermal effusivity of the optimized composites exceeded that of chamotte brick by more than 50%. The highest flexural (12.68 MPa) and compressive (86.18 MPa) strengths were achieved in the composite containing 20 wt.% steel chips, prior to thermal exposure. Microstructural observations revealed the diverse geometry of the steel chips and arrangement of the chamotte particles. These findings highlight the potential of incorporating metallic waste materials into geopolymer systems to develop multifunctional composites with improved thermal storage capacity and mechanical resilience.

Název v anglickém jazyce

Effect of Waste Metal and Chamotte Fillers on the Thermal and Mechanical Properties of Geopolymer Composites for Energy Storage Applications

Popis výsledku anglicky

This study investigates the effects of varying filler content on the thermal and mechanical performance of metakaolinite-based geopolymer composites designed for thermal energy storage applications. The composites were formulated using a geopolymer binder, combined with a thermally stable filler (ground chamotte) and a thermal energy storage filler (waste steel chips) in different proportions. Chamotte content within the binder matrix (binder + chamotte) ranged from 20 to 40 wt.%, while steel chip content varied from 0 to 40 wt.% of the total composite mass. The thermal properties of the composites were evaluated at room temperature and compared with conventional reference materials, including Ultraboard, chamotte brick, and magnetite brick. Mechanical performance, specifically flexural and compressive strength, was evaluated at room temperature and after exposure to elevated temperatures (800 and 1100 °C), followed by two cooling regimes, slow furnace cooling and rapid water quenching. Microstructural characterization via optical microscopy was used to examine filler dispersion and matrix–filler interactions. The results showed that the thermal effusivity of the optimized composites exceeded that of chamotte brick by more than 50%. The highest flexural (12.68 MPa) and compressive (86.18 MPa) strengths were achieved in the composite containing 20 wt.% steel chips, prior to thermal exposure. Microstructural observations revealed the diverse geometry of the steel chips and arrangement of the chamotte particles. These findings highlight the potential of incorporating metallic waste materials into geopolymer systems to develop multifunctional composites with improved thermal storage capacity and mechanical resilience.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20500 - Materials engineering

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2025

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

MATERIALS>

ISSN

1996-1944

e-ISSN

—

Svazek periodika

18

Číslo periodika v rámci svazku

16

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

21

Strana od-do

—

Kód UT WoS článku

001558003500001

EID výsledku v databázi Scopus

2-s2.0-105014324102