Comparative investigation of acetaminophen degradation in aqueous solution by UV/Chlorine and UV/H2O2 processes: Kinetics and toxicity assessment, process feasibility and products identification

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F46747885%3A24620%2F21%3A00008879" target="_blank" >RIV/46747885:24620/21:00008879 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S0045653521019275" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0045653521019275</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.chemosphere.2021.131455" target="_blank" >10.1016/j.chemosphere.2021.131455</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Comparative investigation of acetaminophen degradation in aqueous solution by UV/Chlorine and UV/H2O2 processes: Kinetics and toxicity assessment, process feasibility and products identification

Popis výsledku v původním jazyce

The degradation of acetaminophen (ACM) was comparatively studied by UV/chlorine and UV/H2O2 systems. An apparent reduction in the removal rate was observed above the optimum pH levels of 7.0 and 3.0 in UV/chlorine and UV/H2O2 processes, respectively. The relative contribution of each oxidizing agent in ACM removal using the two advanced oxidation processes (AOPs) was evaluated. Even though hydroxyl radicals, with the contribution percentage of 90.1%, were determined as the primary oxidizing species in ACM removal using the UV/H2O2 process, reactive chlorine species (RCS), with 43.8% of contribution percentage, were also found to play a pivotal role in ACM removal using the UV/chlorine process. For instance, dichlorine radical (Cl2•-) showed an acceptable contribution percentage of 32.2% in the degradation of ACM by the UV/chlorine process. The rate of ACM degradation significantly rose to 99.9% and 75.6%, as higher amounts of oxidants were used in the UV/chlorine and UV/H2O2 processes, respectively, within 25 min. The introduction of HCO3− ions and humic acid remarkably decreased the rate of ACM degradation in both techniques used in this study. The presence of NO3− and Cl− ions did not considerably affect the removal rate in the UV/chlorine process. The acute toxicity analysis revealed that a more pronounced reduction in the ACM solution toxicity could be achieved by the UV/H2O2 process compared to the UV/chlorine process, which should be ascribed to the formation of chlorinated products in the UV/chlorine treatment. Eventually, plausible oxidation pathways were proposed for each process.

Název v anglickém jazyce

Comparative investigation of acetaminophen degradation in aqueous solution by UV/Chlorine and UV/H2O2 processes: Kinetics and toxicity assessment, process feasibility and products identification

Popis výsledku anglicky

The degradation of acetaminophen (ACM) was comparatively studied by UV/chlorine and UV/H2O2 systems. An apparent reduction in the removal rate was observed above the optimum pH levels of 7.0 and 3.0 in UV/chlorine and UV/H2O2 processes, respectively. The relative contribution of each oxidizing agent in ACM removal using the two advanced oxidation processes (AOPs) was evaluated. Even though hydroxyl radicals, with the contribution percentage of 90.1%, were determined as the primary oxidizing species in ACM removal using the UV/H2O2 process, reactive chlorine species (RCS), with 43.8% of contribution percentage, were also found to play a pivotal role in ACM removal using the UV/chlorine process. For instance, dichlorine radical (Cl2•-) showed an acceptable contribution percentage of 32.2% in the degradation of ACM by the UV/chlorine process. The rate of ACM degradation significantly rose to 99.9% and 75.6%, as higher amounts of oxidants were used in the UV/chlorine and UV/H2O2 processes, respectively, within 25 min. The introduction of HCO3− ions and humic acid remarkably decreased the rate of ACM degradation in both techniques used in this study. The presence of NO3− and Cl− ions did not considerably affect the removal rate in the UV/chlorine process. The acute toxicity analysis revealed that a more pronounced reduction in the ACM solution toxicity could be achieved by the UV/H2O2 process compared to the UV/chlorine process, which should be ascribed to the formation of chlorinated products in the UV/chlorine treatment. Eventually, plausible oxidation pathways were proposed for each process.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10511 - Environmental sciences (social aspects to be 5.7)

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2021

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Chemosphere

ISSN

0045-6535

e-ISSN

—

Svazek periodika

285

Číslo periodika v rámci svazku

December

Stát vydavatele periodika

GB - Spojené království Velké Británie a Severního Irska

Počet stran výsledku

12

Strana od-do

—

Kód UT WoS článku

000703680800001

EID výsledku v databázi Scopus

2-s2.0-85110191503