Insights into the synergistic role of photocatalytic activation of peroxymonosulfate by UVA-LED irradiation over CoFe2O4-rGO nanocomposite towards effective Bisphenol A degradation: Performance, mineralization, and activation mechanism

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F46747885%3A24620%2F23%3A00010077" target="_blank" >RIV/46747885:24620/23:00010077 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S1385894722050355" target="_blank" >https://www.sciencedirect.com/science/article/pii/S1385894722050355</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.cej.2022.139556" target="_blank" >10.1016/j.cej.2022.139556</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Insights into the synergistic role of photocatalytic activation of peroxymonosulfate by UVA-LED irradiation over CoFe2O4-rGO nanocomposite towards effective Bisphenol A degradation: Performance, mineralization, and activation mechanism

Popis výsledku v původním jazyce

In this work, CoFe2O4-reduced graphene oxide (CFO-rGO) nanocomposite was synthesized to activate peroxymonosulfate (PMS) under UVA-LED irradiation. Bisphenol A (BPA) was selected as an emerging pollutant to evaluate the performance of the UVA-LED/CFO-rGO/PMS system. CFO-rGO was characterized by several advanced methods including XRD, FTIR, FESEM, EDX-mapping, TEM, XPS, BET-BJH, Raman spectrometry, VSM, PL, and EIS analyses. The operating factors, the determination of reactive species, and the mechanism were studied and discussed. During 30 min reaction time, more than 99% of BPA was removed by 150 mg/L PMS and 400 mg/L CFO-rGO under mild conditions (pH = 3–9). Bicarbonate ions could inhibit the BPA degradation by scavenging the free radicals. The trapping experiments exhibited that sulfate () and hydroxyl (•OH) radicals were prevailing agents for BPA degradation. Humic acid (HA) and sodium dodecyl sulfate (SDS) had a hindering effect on BPA degradation. CFO-rGO showed a high potential for recyclability up to six cycles. Moreover, the leaching of metals was approximately null for CFO-rGO, indicating that the current nanocomposite is highly stable. We also examined UVA-LED/CFO-rGO/PMS system on other pollutants, as well as real conditions. The results showed high efficiency for all conditions. The UVA-LED/CFO-rGO/PMS process could mineralize 67% of BPA during 80 min reaction time. Intermediates of BPA degradation were identified and their toxicity was also estimated. This work enlightened the ferrite catalysts‘ importance in activating PMS under UVA-LED irradiation for emerging pollutants wastewater remediation.

Název v anglickém jazyce

Insights into the synergistic role of photocatalytic activation of peroxymonosulfate by UVA-LED irradiation over CoFe2O4-rGO nanocomposite towards effective Bisphenol A degradation: Performance, mineralization, and activation mechanism

Popis výsledku anglicky

In this work, CoFe2O4-reduced graphene oxide (CFO-rGO) nanocomposite was synthesized to activate peroxymonosulfate (PMS) under UVA-LED irradiation. Bisphenol A (BPA) was selected as an emerging pollutant to evaluate the performance of the UVA-LED/CFO-rGO/PMS system. CFO-rGO was characterized by several advanced methods including XRD, FTIR, FESEM, EDX-mapping, TEM, XPS, BET-BJH, Raman spectrometry, VSM, PL, and EIS analyses. The operating factors, the determination of reactive species, and the mechanism were studied and discussed. During 30 min reaction time, more than 99% of BPA was removed by 150 mg/L PMS and 400 mg/L CFO-rGO under mild conditions (pH = 3–9). Bicarbonate ions could inhibit the BPA degradation by scavenging the free radicals. The trapping experiments exhibited that sulfate () and hydroxyl (•OH) radicals were prevailing agents for BPA degradation. Humic acid (HA) and sodium dodecyl sulfate (SDS) had a hindering effect on BPA degradation. CFO-rGO showed a high potential for recyclability up to six cycles. Moreover, the leaching of metals was approximately null for CFO-rGO, indicating that the current nanocomposite is highly stable. We also examined UVA-LED/CFO-rGO/PMS system on other pollutants, as well as real conditions. The results showed high efficiency for all conditions. The UVA-LED/CFO-rGO/PMS process could mineralize 67% of BPA during 80 min reaction time. Intermediates of BPA degradation were identified and their toxicity was also estimated. This work enlightened the ferrite catalysts‘ importance in activating PMS under UVA-LED irradiation for emerging pollutants wastewater remediation.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20402 - Chemical process engineering

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Chemical Engineering Journal

ISSN

1385-8947

e-ISSN

—

Svazek periodika

453

Číslo periodika v rámci svazku

1

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

16

Strana od-do

—

Kód UT WoS článku

000876980700005

EID výsledku v databázi Scopus

2-s2.0-85140059857