Metal-organic framework-based nanostructured catalysts: Applications in efficient organic transformations

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F46747885%3A24620%2F23%3A00012261" target="_blank" >RIV/46747885:24620/23:00012261 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S2468823123003012" target="_blank" >https://www.sciencedirect.com/science/article/pii/S2468823123003012</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.mcat.2023.113217" target="_blank" >10.1016/j.mcat.2023.113217</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Metal-organic framework-based nanostructured catalysts: Applications in efficient organic transformations

Popis výsledku v původním jazyce

In the heterogeneous catalyst domain, there has been an incessant demand in recent decades with a focus on introducing environmentally friendly and sustainable materials. Because of their distinct structural properties, metal-organic frameworks (MOFs) are emerging as a new class of active materials for organic reactions; sophisticated hybrid catalytic materials can now be fabricated with improved recyclability, separability, and activity for specific organic processes by integrating MOFs with metallic nanoparticles. Herein, we deliberate on several MOF-based nanostructured catalysts that facilitate selected organic transformations. Examples comprise, among others, the Baeyer-Villiger oxidation, cyanation of aldehydes, cycloalkane oxidation, epoxidation of cyclohexenes, esterification, Heck reaction, tandem reactions, Sonogashira and Suzuki-Miyaura cross-coupling reactions, which exploit the catalysts‘ reactivity, reusability, and interactions with the inherent properties of the deployed MOF-based nanostructured catalysts. The benefits, shortcomings, reusability, and efficiency aspects of the introduced catalysts are reviewed. A succinct conclusion is offered, along with a commentary on the major hurdles encountered today and prospective future research needs related to the MOF-based catalysts.

Název v anglickém jazyce

Metal-organic framework-based nanostructured catalysts: Applications in efficient organic transformations

Popis výsledku anglicky

In the heterogeneous catalyst domain, there has been an incessant demand in recent decades with a focus on introducing environmentally friendly and sustainable materials. Because of their distinct structural properties, metal-organic frameworks (MOFs) are emerging as a new class of active materials for organic reactions; sophisticated hybrid catalytic materials can now be fabricated with improved recyclability, separability, and activity for specific organic processes by integrating MOFs with metallic nanoparticles. Herein, we deliberate on several MOF-based nanostructured catalysts that facilitate selected organic transformations. Examples comprise, among others, the Baeyer-Villiger oxidation, cyanation of aldehydes, cycloalkane oxidation, epoxidation of cyclohexenes, esterification, Heck reaction, tandem reactions, Sonogashira and Suzuki-Miyaura cross-coupling reactions, which exploit the catalysts‘ reactivity, reusability, and interactions with the inherent properties of the deployed MOF-based nanostructured catalysts. The benefits, shortcomings, reusability, and efficiency aspects of the introduced catalysts are reviewed. A succinct conclusion is offered, along with a commentary on the major hurdles encountered today and prospective future research needs related to the MOF-based catalysts.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10403 - Physical chemistry

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Molecular Catalysis

ISSN

2468-8231

e-ISSN

—

Svazek periodika

546

Číslo periodika v rámci svazku

July

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

26

Strana od-do

—

Kód UT WoS článku

001008733100001

EID výsledku v databázi Scopus

2-s2.0-85160287785