Influence of Nanoparticles on the Dielectric Response of a Single Component Resin Based on Polyesterimide
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F49777513%3A23220%2F22%3A43965216" target="_blank" >RIV/49777513:23220/22:43965216 - isvavai.cz</a>
Výsledek na webu
<a href="https://www.mdpi.com/2073-4360/14/11/2202" target="_blank" >https://www.mdpi.com/2073-4360/14/11/2202</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.3390/polym14112202" target="_blank" >10.3390/polym14112202</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Influence of Nanoparticles on the Dielectric Response of a Single Component Resin Based on Polyesterimide
Popis výsledku v původním jazyce
The influence of various types of nanoparticle fillers with the same diameter of 20 nm were separately incorporated into a single component impregnating resin based on a polyesterimide (PEI) matrix and its subsequent changes in complex relative permittivity were studied. In this paper, nanoparticles of Al2O3 and ZnO were dispersed into PEI (with 0.5 and 1 wt.%) to prepare nanocomposite polymer. Dielectric frequency spectroscopy was used to measure the dependence of the real and imaginary parts of complex relative permittivity within the frequency range of 1 mHz to 1 MHz at a temperature range from +20 ◦C to +120 ◦C. The presence of weight concentration of nanoparticles in the PEI resin has an impact on the segmental dynamics of the polymer chain and changed the charge distribution in the given system. The changes detected in the 1H NMR spectra confirm that dispersed nanoparticles in PEI lead to the formation of loose structures, which results in higher polymer chain mobility. A shift of the local relaxation peaks, corresponding to the α-relaxation process, and higher mobility of the polymer chains in the spectra of imaginary permittivity of the investigated nanocomposites was observed.
Název v anglickém jazyce
Influence of Nanoparticles on the Dielectric Response of a Single Component Resin Based on Polyesterimide
Popis výsledku anglicky
The influence of various types of nanoparticle fillers with the same diameter of 20 nm were separately incorporated into a single component impregnating resin based on a polyesterimide (PEI) matrix and its subsequent changes in complex relative permittivity were studied. In this paper, nanoparticles of Al2O3 and ZnO were dispersed into PEI (with 0.5 and 1 wt.%) to prepare nanocomposite polymer. Dielectric frequency spectroscopy was used to measure the dependence of the real and imaginary parts of complex relative permittivity within the frequency range of 1 mHz to 1 MHz at a temperature range from +20 ◦C to +120 ◦C. The presence of weight concentration of nanoparticles in the PEI resin has an impact on the segmental dynamics of the polymer chain and changed the charge distribution in the given system. The changes detected in the 1H NMR spectra confirm that dispersed nanoparticles in PEI lead to the formation of loose structures, which results in higher polymer chain mobility. A shift of the local relaxation peaks, corresponding to the α-relaxation process, and higher mobility of the polymer chains in the spectra of imaginary permittivity of the investigated nanocomposites was observed.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
20201 - Electrical and electronic engineering
Návaznosti výsledku
Projekt
—
Návaznosti
S - Specificky vyzkum na vysokych skolach
Ostatní
Rok uplatnění
2022
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Polymers
ISSN
2073-4360
e-ISSN
2073-4360
Svazek periodika
14
Číslo periodika v rámci svazku
11
Stát vydavatele periodika
CH - Švýcarská konfederace
Počet stran výsledku
13
Strana od-do
1-13
Kód UT WoS článku
000808713700001
EID výsledku v databázi Scopus
—