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Evaluation of Selected Cellulose Macromolecular Properties after Its Chemical Treatment Using Size Exclusion Chromatography

Identifikátory výsledku

  • Kód výsledku v IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60460709%3A41320%2F23%3A97009" target="_blank" >RIV/60460709:41320/23:97009 - isvavai.cz</a>

  • Výsledek na webu

    <a href="http://dx.doi.org/10.3390/polym15030573" target="_blank" >http://dx.doi.org/10.3390/polym15030573</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.3390/polym15030573" target="_blank" >10.3390/polym15030573</a>

Alternativní jazyky

  • Jazyk výsledku

    angličtina

  • Název v původním jazyce

    Evaluation of Selected Cellulose Macromolecular Properties after Its Chemical Treatment Using Size Exclusion Chromatography

  • Popis výsledku v původním jazyce

    This work evaluates the effect of using selected inorganic chemicals as the main components of waterborne wood preservative systems on the degradation of the cellulose constituent in wood from model samples. The polymeric properties of cellulose and the homogeneity of the degradation process primarily reflect very well the degree of cellulose deterioration. Whatman papers, as pure cellulose model samples, were impregnated with 10 different 5 wt% solutions of inorganic salts and distilled water and consequently subjected to wet-thermal accelerated aging (T = 85 degrees C, RH = 65%, for 30 days). The samples were then derivatized to cellulose tricarbanilates (CTCs) through two different procedures (by precipitation in a methanol-water mixture/by evaporation of pyridine from the reaction mixture) and finally analyzed using size exclusion chromatography (SEC). Chemically treated and aged cellulose samples showed different changes in the degree of polymerization (DP) and polydispersity (PD) in terms of untreated non-aged standard caused by different ongoing degradation reactions, such as dehydration, hydrolysis, oxidation, and crosslinking. In general, the lowest degradation rate after treatment by chemicals and after accelerated aging was observed in samples treated by borates, NaCl, and ZnSO4 center dot 7H(2)O. The greatest depolymerization after treatment and after accelerated aging was caused by sulphates containing NH4+, Cu2+, and Fe3+ cations, with aging by NH4Cl and (NH4)(2)HPO4-treated samples also leading to significant depolymerization. The higher DP values are linked to the precipitated method of CTC preparation, though not for chlorides and phosphates. PD is also generally higher in precipitated and aged samples and is heavily influenced by the presence of low molecular weight products. This paper brings new insights regarding the complex evaluation of the polymeric properties of degraded cellulose by considering all important factors affecting the sample and the analysis itself through the use of statistics. From the statistical point of view, the influences of all factors (solution, aging, method) and their interactions (except aging*method) on DP are statistically significant. The influence of the sample processing method used for analysis of the desired results becomes important mainly in practice. This work recommends the evaporation method for more accurate description of more degraded cellulose.

  • Název v anglickém jazyce

    Evaluation of Selected Cellulose Macromolecular Properties after Its Chemical Treatment Using Size Exclusion Chromatography

  • Popis výsledku anglicky

    This work evaluates the effect of using selected inorganic chemicals as the main components of waterborne wood preservative systems on the degradation of the cellulose constituent in wood from model samples. The polymeric properties of cellulose and the homogeneity of the degradation process primarily reflect very well the degree of cellulose deterioration. Whatman papers, as pure cellulose model samples, were impregnated with 10 different 5 wt% solutions of inorganic salts and distilled water and consequently subjected to wet-thermal accelerated aging (T = 85 degrees C, RH = 65%, for 30 days). The samples were then derivatized to cellulose tricarbanilates (CTCs) through two different procedures (by precipitation in a methanol-water mixture/by evaporation of pyridine from the reaction mixture) and finally analyzed using size exclusion chromatography (SEC). Chemically treated and aged cellulose samples showed different changes in the degree of polymerization (DP) and polydispersity (PD) in terms of untreated non-aged standard caused by different ongoing degradation reactions, such as dehydration, hydrolysis, oxidation, and crosslinking. In general, the lowest degradation rate after treatment by chemicals and after accelerated aging was observed in samples treated by borates, NaCl, and ZnSO4 center dot 7H(2)O. The greatest depolymerization after treatment and after accelerated aging was caused by sulphates containing NH4+, Cu2+, and Fe3+ cations, with aging by NH4Cl and (NH4)(2)HPO4-treated samples also leading to significant depolymerization. The higher DP values are linked to the precipitated method of CTC preparation, though not for chlorides and phosphates. PD is also generally higher in precipitated and aged samples and is heavily influenced by the presence of low molecular weight products. This paper brings new insights regarding the complex evaluation of the polymeric properties of degraded cellulose by considering all important factors affecting the sample and the analysis itself through the use of statistics. From the statistical point of view, the influences of all factors (solution, aging, method) and their interactions (except aging*method) on DP are statistically significant. The influence of the sample processing method used for analysis of the desired results becomes important mainly in practice. This work recommends the evaporation method for more accurate description of more degraded cellulose.

Klasifikace

  • Druh

    J<sub>imp</sub> - Článek v periodiku v databázi Web of Science

  • CEP obor

  • OECD FORD obor

    10404 - Polymer science

Návaznosti výsledku

  • Projekt

  • Návaznosti

    S - Specificky vyzkum na vysokych skolach

Ostatní

  • Rok uplatnění

    2023

  • Kód důvěrnosti údajů

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Údaje specifické pro druh výsledku

  • Název periodika

    POLYMERS

  • ISSN

    2073-4360

  • e-ISSN

    2073-4360

  • Svazek periodika

    15

  • Číslo periodika v rámci svazku

    3

  • Stát vydavatele periodika

    CH - Švýcarská konfederace

  • Počet stran výsledku

    15

  • Strana od-do

    1-15

  • Kód UT WoS článku

    000929546900001

  • EID výsledku v databázi Scopus

    2-s2.0-85147963333