Experimental study of hydrocarbon structure effects on the composition of its pyrolysis products

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F10%3A00023334" target="_blank" >RIV/60461373:22310/10:00023334 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Experimental study of hydrocarbon structure effects on the composition of its pyrolysis products

Popis výsledku v původním jazyce

Pyrolysis experiments aimed at measuring product yields and conversion of various hydrocarbons were carried out in a micro-pyrolysis laboratory reactor. Standard pyrolysis conditions were used for all samples-810 degrees C, 400 kPa and 0.2-0.4 s residence time in the reaction zone. Analysis of products was performed by on-line GC/FID/TCD. All pyrolysis products from hydrogen to pyrolysis oil were detected either individually or by fractions. Detailed compositions of the pyrolysis products of 56 hydrocarbons were obtained and are included completely in the article. The study involved hydrocarbons, which represent the wide structural variability, including linear, branched, cyclic, aromatic and unsaturated. Measured data were used to identify important relationships between structural parameters and product yields. Trends of important product yields, depending on the carbon number, molecule saturation, substitution, ring presence and substitution or a substituent size are presented.

Název v anglickém jazyce

Experimental study of hydrocarbon structure effects on the composition of its pyrolysis products

Popis výsledku anglicky

Pyrolysis experiments aimed at measuring product yields and conversion of various hydrocarbons were carried out in a micro-pyrolysis laboratory reactor. Standard pyrolysis conditions were used for all samples-810 degrees C, 400 kPa and 0.2-0.4 s residence time in the reaction zone. Analysis of products was performed by on-line GC/FID/TCD. All pyrolysis products from hydrogen to pyrolysis oil were detected either individually or by fractions. Detailed compositions of the pyrolysis products of 56 hydrocarbons were obtained and are included completely in the article. The study involved hydrocarbons, which represent the wide structural variability, including linear, branched, cyclic, aromatic and unsaturated. Measured data were used to identify important relationships between structural parameters and product yields. Trends of important product yields, depending on the carbon number, molecule saturation, substitution, ring presence and substitution or a substituent size are presented.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CI - Průmyslová chemie a chemické inženýrství

OECD FORD obor

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Projekt

<a href="/cs/project/GA104%2F08%2F1288" target="_blank" >GA104/08/1288: Reaktivita uhlovodíků při pyrolýze a selektivita jejich tepelného štěpení v závislosti na struktuře</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2010

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS

ISSN

0165-2370

e-ISSN

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Svazek periodika

87

Číslo periodika v rámci svazku

2

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

10

Strana od-do

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Kód UT WoS článku

000276114200005

EID výsledku v databázi Scopus

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