Use of Boron-Doped Diamond Electrode in Electrochemical Generation and Application of Ferrate

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F11%3A43892413" target="_blank" >RIV/60461373:22310/11:43892413 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1002/9781118062364.ch4" target="_blank" >http://dx.doi.org/10.1002/9781118062364.ch4</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/9781118062364.ch4" target="_blank" >10.1002/9781118062364.ch4</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Use of Boron-Doped Diamond Electrode in Electrochemical Generation and Application of Ferrate

Popis výsledku v původním jazyce

Significant advances in terms of the optimization of parameters such as the anode material and operating conditions have been made regarding the electrochemical synthesis of ferrate. However, the mechanism of the Fe(III) oxidation to yield ferrate stillneeds to be fully understood. The use of classical electrochemical techniques may not be sufficient to explore the mechanism because the reaction of Fe(III) to Fe(VI) is overlapped by oxygen evolution. Hence, spectroscopic approaches are currently beingused to gain insight on the processes occurring at the electrode surface. Two relatively new synthesis approaches, i.e., the employment of molten hydroxides as the electrolysis environment and the utilization of inert anodes, are currently being pursuedto minimize the influence of the anode material and the oxygen evolution in synthesizing ferrate. Studies reporting the use of BDD anode to synthesize ferrate are forthcoming. The efficiency of the synthesis is greatly influenced by the a

Název v anglickém jazyce

Use of Boron-Doped Diamond Electrode in Electrochemical Generation and Application of Ferrate

Popis výsledku anglicky

Significant advances in terms of the optimization of parameters such as the anode material and operating conditions have been made regarding the electrochemical synthesis of ferrate. However, the mechanism of the Fe(III) oxidation to yield ferrate stillneeds to be fully understood. The use of classical electrochemical techniques may not be sufficient to explore the mechanism because the reaction of Fe(III) to Fe(VI) is overlapped by oxygen evolution. Hence, spectroscopic approaches are currently beingused to gain insight on the processes occurring at the electrode surface. Two relatively new synthesis approaches, i.e., the employment of molten hydroxides as the electrolysis environment and the utilization of inert anodes, are currently being pursuedto minimize the influence of the anode material and the oxygen evolution in synthesizing ferrate. Studies reporting the use of BDD anode to synthesize ferrate are forthcoming. The efficiency of the synthesis is greatly influenced by the a

Druh

B - Odborná kniha

CEP obor

CG - Elektrochemie

OECD FORD obor

—

Projekt

—

Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2011

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

ISBN

978-0-470-48758-7

Počet stran knihy

680

Název nakladatele

John Wiley &amp; Sons

Místo vydání

Singapore

Kód UT WoS knihy

—