Immobilization of pyridinium nitrate and its application for the catalytic converting of ?-pinene oxide

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F13%3A43894065" target="_blank" >RIV/60461373:22310/13:43894065 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Immobilization of pyridinium nitrate and its application for the catalytic converting of ?-pinene oxide

Popis výsledku v původním jazyce

In this paper, differences among the catalytic effects of individual ammonium nitrates and influences of the catalysts used either in homogeneous and, moreover, pyridinium nitrate in heterogeneous forms of the catalytic converting of ?-pinene oxide to perillic alcohol were studied. A special attention was paid to the heterogeneously catalyzed reaction where the representative of the used catalysts, pyridinium nitrate, was immobilized on various supports?mesoporous molecular sieves (MCM-41, SBA-15), silica and smectites (hectorite, montmorillonite K-10 and bentonite). Based on the obtained results, the individual influences on the course of the catalytic splitting, namely the properties and modifications of supporting materials were discussed. The bestresults using the catalyst immobilized on hectorite were achieved. The maximum relative concentration was 64 % for perillic alcohol and 17 % for perillic alcohol isomers 17 %.

Název v anglickém jazyce

Immobilization of pyridinium nitrate and its application for the catalytic converting of ?-pinene oxide

Popis výsledku anglicky

In this paper, differences among the catalytic effects of individual ammonium nitrates and influences of the catalysts used either in homogeneous and, moreover, pyridinium nitrate in heterogeneous forms of the catalytic converting of ?-pinene oxide to perillic alcohol were studied. A special attention was paid to the heterogeneously catalyzed reaction where the representative of the used catalysts, pyridinium nitrate, was immobilized on various supports?mesoporous molecular sieves (MCM-41, SBA-15), silica and smectites (hectorite, montmorillonite K-10 and bentonite). Based on the obtained results, the individual influences on the course of the catalytic splitting, namely the properties and modifications of supporting materials were discussed. The bestresults using the catalyst immobilized on hectorite were achieved. The maximum relative concentration was 64 % for perillic alcohol and 17 % for perillic alcohol isomers 17 %.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CC - Organická chemie

OECD FORD obor

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Projekt

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Návaznosti

S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2013

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Reaction Kinetics Mechanisms and Catalysis

ISSN

1878-5190

e-ISSN

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Svazek periodika

108

Číslo periodika v rámci svazku

1

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

11

Strana od-do

69-79

Kód UT WoS článku

000313370800006

EID výsledku v databázi Scopus

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