Isomerization of alfa-?pinene oxide using Fe-?supported catalysts: Selective synthesis of campholenic aldehyde
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F14%3A43898262" target="_blank" >RIV/60461373:22310/14:43898262 - isvavai.cz</a>
Výsledek na webu
<a href="http://dx.doi.org/10.1016/j.apcata.2013.10.044" target="_blank" >http://dx.doi.org/10.1016/j.apcata.2013.10.044</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.apcata.2013.10.044" target="_blank" >10.1016/j.apcata.2013.10.044</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Isomerization of alfa-?pinene oxide using Fe-?supported catalysts: Selective synthesis of campholenic aldehyde
Popis výsledku v původním jazyce
alfa-?Pinene oxide, an oxygenated deriv. of alfa-?pinene, can be converted into various valuable substances useful as flavor, fragrance and pharmaceutical compds. Campholenic aldehyde is one of the most desired products of alfa-?pinene oxide isomerization being a valuable intermediate for the prodn. of sandalwood-?like fragrances. Iron modified zeolites Beta-?75 and ZSM-?5, mesoporous material MCM-?41, silica and alumina were prepd. by two methods (impregnation and solid-?state ion exchange) and testedfor selective prepn. of campholenic aldehyde by isomerization of alfa-?pinene oxide. The characterization of tested catalyst was carried out using scanning electron microscope anal., nitrogen adsorption measurements, pyridine adsorption-?desorption withFTIR, X-?ray absorption spectroscopy measurements, XPS-?anal., 29Si MAS NMR and 27Al MAS NMR and X-?ray diffraction. The isomerization of alfa-?pinene oxide was carried out in toluene as a solvent at 70 °C. The main properties influencing
Název v anglickém jazyce
Isomerization of alfa-?pinene oxide using Fe-?supported catalysts: Selective synthesis of campholenic aldehyde
Popis výsledku anglicky
alfa-?Pinene oxide, an oxygenated deriv. of alfa-?pinene, can be converted into various valuable substances useful as flavor, fragrance and pharmaceutical compds. Campholenic aldehyde is one of the most desired products of alfa-?pinene oxide isomerization being a valuable intermediate for the prodn. of sandalwood-?like fragrances. Iron modified zeolites Beta-?75 and ZSM-?5, mesoporous material MCM-?41, silica and alumina were prepd. by two methods (impregnation and solid-?state ion exchange) and testedfor selective prepn. of campholenic aldehyde by isomerization of alfa-?pinene oxide. The characterization of tested catalyst was carried out using scanning electron microscope anal., nitrogen adsorption measurements, pyridine adsorption-?desorption withFTIR, X-?ray absorption spectroscopy measurements, XPS-?anal., 29Si MAS NMR and 27Al MAS NMR and X-?ray diffraction. The isomerization of alfa-?pinene oxide was carried out in toluene as a solvent at 70 °C. The main properties influencing
Klasifikace
Druh
J<sub>x</sub> - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
CEP obor
CC - Organická chemie
OECD FORD obor
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Návaznosti výsledku
Projekt
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Návaznosti
S - Specificky vyzkum na vysokych skolach
Ostatní
Rok uplatnění
2014
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
APPLIED CATALYSIS A-GENERAL
ISSN
0926-860X
e-ISSN
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Svazek periodika
470
Číslo periodika v rámci svazku
neuveden
Stát vydavatele periodika
NL - Nizozemsko
Počet stran výsledku
15
Strana od-do
162-176
Kód UT WoS článku
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EID výsledku v databázi Scopus
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