The Covalent Functionalization of Layered Black Phosphorus by Nucleophilic Reagents

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F17%3A43913379" target="_blank" >RIV/60461373:22310/17:43913379 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/61989592:15310/17:73584590 RIV/60461373:22810/17:43913379

Výsledek na webu

<a href="http://onlinelibrary.wiley.com/doi/10.1002/ange.201705722/full" target="_blank" >http://onlinelibrary.wiley.com/doi/10.1002/ange.201705722/full</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/anie.201705722" target="_blank" >10.1002/anie.201705722</a>

Jazyk výsledku

angličtina

Název v původním jazyce

The Covalent Functionalization of Layered Black Phosphorus by Nucleophilic Reagents

Popis výsledku v původním jazyce

Layered black phosphorus has been attracting great attention due to its interesting material properties which lead to a plethora of proposed applications. Several approaches are demonstrated here for covalent chemical modifications of layered black phosphorus in order to form P-C and P-O-C bonds. Nucleophilic reagents are highly effective for chemical modification of black phosphorus. Further derivatization approaches investigated were based on radical reactions. These reagents are not as effective as nucleophilic reagents for the surface covalent modification of black phosphorus. The influence of covalent modification on the electronic structure of black phosphorus was investigated using ab initio calculations. Covalent modification exerts a strong effect on the electronic structure including the change of band-gap width and spin polarization.

Název v anglickém jazyce

The Covalent Functionalization of Layered Black Phosphorus by Nucleophilic Reagents

Popis výsledku anglicky

Layered black phosphorus has been attracting great attention due to its interesting material properties which lead to a plethora of proposed applications. Several approaches are demonstrated here for covalent chemical modifications of layered black phosphorus in order to form P-C and P-O-C bonds. Nucleophilic reagents are highly effective for chemical modification of black phosphorus. Further derivatization approaches investigated were based on radical reactions. These reagents are not as effective as nucleophilic reagents for the surface covalent modification of black phosphorus. The influence of covalent modification on the electronic structure of black phosphorus was investigated using ab initio calculations. Covalent modification exerts a strong effect on the electronic structure including the change of band-gap width and spin polarization.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10402 - Inorganic and nuclear chemistry

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

S - Specificky vyzkum na vysokych skolach

Rok uplatnění

2017

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Angewandte Chemie-International Edition

ISSN

1433-7851

e-ISSN

—

Svazek periodika

56

Číslo periodika v rámci svazku

33

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

6

Strana od-do

9891-9896

Kód UT WoS článku

000406798700045

EID výsledku v databázi Scopus

2-s2.0-85024365279