alpha-keto-beta-diimine nickel-catalyzed olefin polymerization: Effect of ortho-aryl substituents and preparation of stereoblock copolymers
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F17%3A43913689" target="_blank" >RIV/60461373:22310/17:43913689 - isvavai.cz</a>
Nalezeny alternativní kódy
RIV/00216208:11310/17:10361117
Výsledek na webu
<a href="http://onlinelibrary.wiley.com/doi/10.1002/pola.28206/full" target="_blank" >http://onlinelibrary.wiley.com/doi/10.1002/pola.28206/full</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/pola.28631" target="_blank" >10.1002/pola.28631</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
alpha-keto-beta-diimine nickel-catalyzed olefin polymerization: Effect of ortho-aryl substituents and preparation of stereoblock copolymers
Popis výsledku v původním jazyce
A series of -keto--diimine nickel complexes (Ar-N=C(CH3)-C(O)-C(CH3)=N-Ar)NiBr2; Ar=2,6-R-C6H3-, R=Me, Et, iPr, and Ar=2,4,6-Me-3-C6H3-) was prepared. All corresponding ligands are unstable even under an inert atmosphere and in a freezer. Stable copper complex intermediates of ligand synthesis and ethyl substituted nickel complex were isolated and characterized by X-ray. All nickel complexes were used for the polymerization of ethene, propylene, and hex-1-ene to investigate their livingness and the extent of chain-walking. Low-temperature propene polymerization with less bulky ortho-substituents was less isospecific than the one with isopropyl derivative. Propene stereoblock copolymers were prepared by iPr derivative combining the polymerization at low temperature to prepare isotactic polypropylene (PP) block and at a higher temperature, supporting chain-walking, to obtain amorphous regioirregular PP block. Alternatively, a copolymerization of propene with ethene was used for the preparation of amorphous block. (c) 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017, 55, 2440-2449
Název v anglickém jazyce
alpha-keto-beta-diimine nickel-catalyzed olefin polymerization: Effect of ortho-aryl substituents and preparation of stereoblock copolymers
Popis výsledku anglicky
A series of -keto--diimine nickel complexes (Ar-N=C(CH3)-C(O)-C(CH3)=N-Ar)NiBr2; Ar=2,6-R-C6H3-, R=Me, Et, iPr, and Ar=2,4,6-Me-3-C6H3-) was prepared. All corresponding ligands are unstable even under an inert atmosphere and in a freezer. Stable copper complex intermediates of ligand synthesis and ethyl substituted nickel complex were isolated and characterized by X-ray. All nickel complexes were used for the polymerization of ethene, propylene, and hex-1-ene to investigate their livingness and the extent of chain-walking. Low-temperature propene polymerization with less bulky ortho-substituents was less isospecific than the one with isopropyl derivative. Propene stereoblock copolymers were prepared by iPr derivative combining the polymerization at low temperature to prepare isotactic polypropylene (PP) block and at a higher temperature, supporting chain-walking, to obtain amorphous regioirregular PP block. Alternatively, a copolymerization of propene with ethene was used for the preparation of amorphous block. (c) 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017, 55, 2440-2449
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
10404 - Polymer science
Návaznosti výsledku
Projekt
<a href="/cs/project/GC15-15887J" target="_blank" >GC15-15887J: KATALYZÁTORY PRO ŘÍZENÉ VĚTVENÍ POLYOLEFINŮ. PROPOJENÍ TEORIE A EXPERIMENTU.</a><br>
Návaznosti
S - Specificky vyzkum na vysokych skolach
Ostatní
Rok uplatnění
2017
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Journal of polymer science. Part A, Polymer chemistry
ISSN
0887-624X
e-ISSN
—
Svazek periodika
55
Číslo periodika v rámci svazku
15
Stát vydavatele periodika
US - Spojené státy americké
Počet stran výsledku
10
Strana od-do
2440-2449
Kód UT WoS článku
000403815500003
EID výsledku v databázi Scopus
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