Bench-Stable Sulfoxide-Based Boronates: Preparation and Application in a Tandem Suzuki Reaction

Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F18%3A43917168" target="_blank" >RIV/60461373:22310/18:43917168 - isvavai.cz</a>
Nalezeny alternativní kódy
RIV/68378271:_____/18:00501726
Výsledek na webu
<a href="https://onlinelibrary.wiley.com/doi/full/10.1002/adsc.201801000" target="_blank" >https://onlinelibrary.wiley.com/doi/full/10.1002/adsc.201801000</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/adsc.201801000" target="_blank" >10.1002/adsc.201801000</a>

Jazyk výsledku
angličtina
Název v původním jazyce
Bench-Stable Sulfoxide-Based Boronates: Preparation and Application in a Tandem Suzuki Reaction
Popis výsledku v původním jazyce
A set of novel aromatic and heteroaromatic bench-stable sulfoxide-based boronates was prepared. The structure of the boronates was established by means of X-ray crystallography, and the prepared boronates were successively used in Suzuki cross-coupling reactions under different conditions. We also developed a tandem Suzuki reaction so that a base is generated during the nucleophilic addition of Grignard reagents to 4-bromobenzaldehyde. The formed intermediates were smoothly coupled with the prepared boronates and the boronic acids under external base-free conditions.
Název v anglickém jazyce
Bench-Stable Sulfoxide-Based Boronates: Preparation and Application in a Tandem Suzuki Reaction
Popis výsledku anglicky
A set of novel aromatic and heteroaromatic bench-stable sulfoxide-based boronates was prepared. The structure of the boronates was established by means of X-ray crystallography, and the prepared boronates were successively used in Suzuki cross-coupling reactions under different conditions. We also developed a tandem Suzuki reaction so that a base is generated during the nucleophilic addition of Grignard reagents to 4-bromobenzaldehyde. The formed intermediates were smoothly coupled with the prepared boronates and the boronic acids under external base-free conditions.

Projekt
<a href="/cs/project/GA18-12150S" target="_blank" >GA18-12150S: Syntéza a charakterizace polovodivých supramolekul nového typu a jejich použití pro přípravu organických tranzistorů (OFET)</a><br>
Návaznosti
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění
2018
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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