Coordination chemistry of 2D and layered gray arsenic: photochemical functionalization with chromium hexacarbonyl

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F19%3A43918136" target="_blank" >RIV/60461373:22310/19:43918136 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/00216305:26620/19:PU133215

Výsledek na webu

<a href="https://www.nature.com/articles/s41427-019-0142-x" target="_blank" >https://www.nature.com/articles/s41427-019-0142-x</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1038/s41427-019-0142-x" target="_blank" >10.1038/s41427-019-0142-x</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Coordination chemistry of 2D and layered gray arsenic: photochemical functionalization with chromium hexacarbonyl

Popis výsledku v původním jazyce

The functionalization of layered materials is one of the current challenges in material science. Exfoliated rhombohedral (gray) arsenic represents a promising layered material for the fabrication of electronic devices and sensors; however, synthetic protocols for tuning its properties or protecting the surface by covalent functionalization are not known. In this communication, we present its covalent functionalization accompanied by the exfoliation of rhombohedral arsenic in the presence of ultraviolet light irradiation and chromium hexacarbonyl. During this modification, the arsenic atoms act as ligands to the chromium metal center. We believe that this study provides a promising approach for the modification of rhombohedral few-layer arsenene and enables its application in various fields, including electronic devices, sensors, and energy devices.

Název v anglickém jazyce

Coordination chemistry of 2D and layered gray arsenic: photochemical functionalization with chromium hexacarbonyl

Popis výsledku anglicky

The functionalization of layered materials is one of the current challenges in material science. Exfoliated rhombohedral (gray) arsenic represents a promising layered material for the fabrication of electronic devices and sensors; however, synthetic protocols for tuning its properties or protecting the surface by covalent functionalization are not known. In this communication, we present its covalent functionalization accompanied by the exfoliation of rhombohedral arsenic in the presence of ultraviolet light irradiation and chromium hexacarbonyl. During this modification, the arsenic atoms act as ligands to the chromium metal center. We believe that this study provides a promising approach for the modification of rhombohedral few-layer arsenene and enables its application in various fields, including electronic devices, sensors, and energy devices.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10402 - Inorganic and nuclear chemistry

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2019

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

NPG ASIA MATERIALS

ISSN

1884-4049

e-ISSN

—

Svazek periodika

11

Číslo periodika v rámci svazku

AUG 23 2019

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

7

Strana od-do

—

Kód UT WoS článku

000483900600001

EID výsledku v databázi Scopus

2-s2.0-85071334455