Alkali Metal Arenides as a Universal Synthetic Tool for Layered 2D Germanene Modification

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F19%3A43918150" target="_blank" >RIV/60461373:22310/19:43918150 - isvavai.cz</a>

Výsledek na webu

<a href="https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201910654" target="_blank" >https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201910654</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/anie.201910654" target="_blank" >10.1002/anie.201910654</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Alkali Metal Arenides as a Universal Synthetic Tool for Layered 2D Germanene Modification

Popis výsledku v původním jazyce

The rediscovery of graphene in 2004 has started an enormous chase in the research of 2D materials. A new family of layered 2D materials consisting of the 14th group elements beyond carbon has already been reported. Here, a new methodology in germanene chemistry is presented using germanane (Ge6H6) as a stable and easily accessible starting material for effective synthesis of novel germanene derivatives. The modification procedure utilizing strong bases-alkali metal arenides-for deprotonation of germanane and its subsequent functionalization with p-nitrobenzyl bromide is described. Functionalization of germanene is confirmed by FT-IR, Raman, and XPS spectroscopy as well as by X-ray diffraction analysis.

Název v anglickém jazyce

Alkali Metal Arenides as a Universal Synthetic Tool for Layered 2D Germanene Modification

Popis výsledku anglicky

The rediscovery of graphene in 2004 has started an enormous chase in the research of 2D materials. A new family of layered 2D materials consisting of the 14th group elements beyond carbon has already been reported. Here, a new methodology in germanene chemistry is presented using germanane (Ge6H6) as a stable and easily accessible starting material for effective synthesis of novel germanene derivatives. The modification procedure utilizing strong bases-alkali metal arenides-for deprotonation of germanane and its subsequent functionalization with p-nitrobenzyl bromide is described. Functionalization of germanene is confirmed by FT-IR, Raman, and XPS spectroscopy as well as by X-ray diffraction analysis.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10402 - Inorganic and nuclear chemistry

Projekt

<a href="/cs/project/GX19-26910X" target="_blank" >GX19-26910X: Chemie ve dvou dimenzích - za hranice grafenu</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2019

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Angewandte Chemie-International Edition

ISSN

1433-7851

e-ISSN

—

Svazek periodika

58

Číslo periodika v rámci svazku

46

Stát vydavatele periodika

DE - Spolková republika Německo

Počet stran výsledku

7

Strana od-do

16517-16522

Kód UT WoS článku

000489496200001

EID výsledku v databázi Scopus

2-s2.0-85073938597