Surface Functionalization of 2D Transition Metal Oxides and Dichalcogenides via Covalent and Non-covalent Bonding for Sustainable Energy and Biomedical Applications

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F20%3A43920411" target="_blank" >RIV/60461373:22310/20:43920411 - isvavai.cz</a>

Výsledek na webu

<a href="https://pubs.acs.org/doi/pdf/10.1021/acsanm.0c00120" target="_blank" >https://pubs.acs.org/doi/pdf/10.1021/acsanm.0c00120</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1021/acsanm.0c00120" target="_blank" >10.1021/acsanm.0c00120</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Surface Functionalization of 2D Transition Metal Oxides and Dichalcogenides via Covalent and Non-covalent Bonding for Sustainable Energy and Biomedical Applications

Popis výsledku v původním jazyce

The interest in two-dimensional (2D) nanomaterials has been increased rapidly after the discovery of graphene. The 2D graphene analogs (2DGAs) with ultrathin-layered feature exhibit a unique property which their bulk counterparts cannot possess. Among various 2D nanomaterials, the transition metal dichalcogenides (TMDs) and transition metal oxides (TMOs) have attracted considerable attention from scientific communities. The availability of various transition metals and their binding states in 2D TMDs and TMOs enable them to show a wide spectrum of properties such as metals to wide band gap semiconductors. Although properties of 2D TMDs and TMOs are excellent, further enhancement of their properties is still required for cutting-edge applications. The surface functionalization of 2DGAs is a potential route for enhancing their properties. The surfaces of 2D TMDs and TMOs could be functionalized with various types of organic or inorganic nanomaterials via covalent or non-covalent interactions. The functionalization may alter the Fermi level of 2D nanomaterials, also having this potential to add extra functionalities to the basis of the fabricated devices using them. In this review, we first introduce and specify the characteristics of 2D TMDs and TMOs as two important 2DGAs. Then, we discuss their limitations and how surface functionalization may enhance their performance. The covalent and non-covalent modes of surface functionalization with organic and inorganic nanomaterials on both 2D TMDs and TMOs are then considered. The current state and challenge of the functionalized 2D TMDs and TMOs are also discussed by their application point of view in energy storage and conversion, sensing, biomedical, catalytic combustion, and (opto)electronic devices. Copyright © 2020 American Chemical Society.

Název v anglickém jazyce

Surface Functionalization of 2D Transition Metal Oxides and Dichalcogenides via Covalent and Non-covalent Bonding for Sustainable Energy and Biomedical Applications

Popis výsledku anglicky

The interest in two-dimensional (2D) nanomaterials has been increased rapidly after the discovery of graphene. The 2D graphene analogs (2DGAs) with ultrathin-layered feature exhibit a unique property which their bulk counterparts cannot possess. Among various 2D nanomaterials, the transition metal dichalcogenides (TMDs) and transition metal oxides (TMOs) have attracted considerable attention from scientific communities. The availability of various transition metals and their binding states in 2D TMDs and TMOs enable them to show a wide spectrum of properties such as metals to wide band gap semiconductors. Although properties of 2D TMDs and TMOs are excellent, further enhancement of their properties is still required for cutting-edge applications. The surface functionalization of 2DGAs is a potential route for enhancing their properties. The surfaces of 2D TMDs and TMOs could be functionalized with various types of organic or inorganic nanomaterials via covalent or non-covalent interactions. The functionalization may alter the Fermi level of 2D nanomaterials, also having this potential to add extra functionalities to the basis of the fabricated devices using them. In this review, we first introduce and specify the characteristics of 2D TMDs and TMOs as two important 2DGAs. Then, we discuss their limitations and how surface functionalization may enhance their performance. The covalent and non-covalent modes of surface functionalization with organic and inorganic nanomaterials on both 2D TMDs and TMOs are then considered. The current state and challenge of the functionalized 2D TMDs and TMOs are also discussed by their application point of view in energy storage and conversion, sensing, biomedical, catalytic combustion, and (opto)electronic devices. Copyright © 2020 American Chemical Society.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10402 - Inorganic and nuclear chemistry

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2020

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

ACS Applied Nano Materials

ISSN

2574-0970

e-ISSN

—

Svazek periodika

3

Číslo periodika v rámci svazku

4

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

28

Strana od-do

3116-3143

Kód UT WoS článku

000529206200002

EID výsledku v databázi Scopus

2-s2.0-85084513659