Switchable PNIPAm/PPyNT Hydrogel for Smart Supercapacitors: External Control of Capacitance for Pulsed Energy Generation or Prolongation of Discharge Time

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F21%3A43922755" target="_blank" >RIV/60461373:22310/21:43922755 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/60461373:22330/21:43922755 RIV/60461373:22340/21:43922755

Výsledek na webu

<a href="https://pubs-acs-org.ezproxy.vscht.cz/doi/10.1021/acsami.1c12228" target="_blank" >https://pubs-acs-org.ezproxy.vscht.cz/doi/10.1021/acsami.1c12228</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1021/acsami.1c12228" target="_blank" >10.1021/acsami.1c12228</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Switchable PNIPAm/PPyNT Hydrogel for Smart Supercapacitors: External Control of Capacitance for Pulsed Energy Generation or Prolongation of Discharge Time

Popis výsledku v původním jazyce

Supercapacitors based on nonresponsive polymer hydrogels are gaining significant attention due to their fabrication simplicity and high potential for wearable electronics. However, the use of smart hydrogels in supercapacitor design remains unexplored. In this work, a smart externally controlled supercapacitor based on a temperature-responsive hydrogel doped with polypyrrole nanotubes (PPyNTs) is proposed. The redistribution of PPyNTs in the poly(N-isopropylacrylamide) (PNIPAm) hydrogel can be reversibly controlled by light illumination or temperature increase, leading to on-demand formation/disruption of the nanotube conductive network, due to release/entrapping of the nanotubes from PNIPAm globule volume on surface. The switchable material was introduced in a supercapacitor design as an active and smart electrode, responsible for external control of charge transport and storage. The created device showed a switchable supercapacitor performance with an ability to significantly and rapidly change capacity under heating/cooling or light illumination. The external trigger was applied for static or dynamic control of supercapacitor behavior: prolongation of discharge time (with constant electric loading) or vice-versa pronounced acceleration of supercapacitor discharge. The proposed smart material-based supercapacitor can find a range of attractive applications in backup energy storage or high power pulse generation.

Název v anglickém jazyce

Switchable PNIPAm/PPyNT Hydrogel for Smart Supercapacitors: External Control of Capacitance for Pulsed Energy Generation or Prolongation of Discharge Time

Popis výsledku anglicky

Supercapacitors based on nonresponsive polymer hydrogels are gaining significant attention due to their fabrication simplicity and high potential for wearable electronics. However, the use of smart hydrogels in supercapacitor design remains unexplored. In this work, a smart externally controlled supercapacitor based on a temperature-responsive hydrogel doped with polypyrrole nanotubes (PPyNTs) is proposed. The redistribution of PPyNTs in the poly(N-isopropylacrylamide) (PNIPAm) hydrogel can be reversibly controlled by light illumination or temperature increase, leading to on-demand formation/disruption of the nanotube conductive network, due to release/entrapping of the nanotubes from PNIPAm globule volume on surface. The switchable material was introduced in a supercapacitor design as an active and smart electrode, responsible for external control of charge transport and storage. The created device showed a switchable supercapacitor performance with an ability to significantly and rapidly change capacity under heating/cooling or light illumination. The external trigger was applied for static or dynamic control of supercapacitor behavior: prolongation of discharge time (with constant electric loading) or vice-versa pronounced acceleration of supercapacitor discharge. The proposed smart material-based supercapacitor can find a range of attractive applications in backup energy storage or high power pulse generation.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20501 - Materials engineering

Projekt

<a href="/cs/project/GA18-26170S" target="_blank" >GA18-26170S: Světlem laditelné konjugované polymery pro vratné spínání vodivosti</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2021

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

ACS Applied Materials and Interfaces

ISSN

1944-8244

e-ISSN

—

Svazek periodika

13

Číslo periodika v rámci svazku

40

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

10

Strana od-do

48030-48039

Kód UT WoS článku

000709458200068

EID výsledku v databázi Scopus

2-s2.0-85117342829