Six-Degree-of-Freedom Steerable Visible-Light-Driven Microsubmarines Using Water as a Fuel: Application for Explosives Decontamination

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F21%3A43924029" target="_blank" >RIV/60461373:22310/21:43924029 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/62156489:43210/21:43919799 RIV/00216305:26620/21:PU141460

Výsledek na webu

<a href="https://onlinelibrary.wiley.com/doi/10.1002/smll.202100294" target="_blank" >https://onlinelibrary.wiley.com/doi/10.1002/smll.202100294</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/smll.202100294" target="_blank" >10.1002/smll.202100294</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Six-Degree-of-Freedom Steerable Visible-Light-Driven Microsubmarines Using Water as a Fuel: Application for Explosives Decontamination

Popis výsledku v původním jazyce

Micro/nanomotors are capable of a wide variety of tasks related, i.e., to biomedical or environmental applications. Light-driven semiconductor-based micromotors are especially appealing, as they can split surrounding water via light irradiation, and therefore, they can move infinitely. However, their motion is typically limited to in-plane motion with four degrees of freedom (4DoF) or even pseudo-1D motion with 2DoF. Herein, magnetically steerable tubular TiO2/Fe3O4/CdS micromotors, termed microsubmarines, with 6DoF motion, based on a fuel-free design where surrounding water acts as fuel upon visible light irradiation, are presented, with an average velocity of 7.9 mu m s(-1). Besides, the generation of radicals via such water splitting aids the photocatalytic chemicals degradation with the potential to use solar radiation. A light-induced self-electrophoretic mechanism is responsible for the self-propulsion and can be used to predict the motion direction based on the structure and composition. Finally, the TiO2/Fe3O4/CdS microsubmarines are tested in a proof-of-concept application of high-energy explosive, e.g., picric acid, photocatalytic degradation, with the best performance owing to the versatility of 6DoF motion, the surface coating with amorphous TiO2 layer, and UV light. The results can help optimize light-active micromotor design for potential national security and environmental application, hydrogen evolution, and target cargo delivery.

Název v anglickém jazyce

Six-Degree-of-Freedom Steerable Visible-Light-Driven Microsubmarines Using Water as a Fuel: Application for Explosives Decontamination

Popis výsledku anglicky

Micro/nanomotors are capable of a wide variety of tasks related, i.e., to biomedical or environmental applications. Light-driven semiconductor-based micromotors are especially appealing, as they can split surrounding water via light irradiation, and therefore, they can move infinitely. However, their motion is typically limited to in-plane motion with four degrees of freedom (4DoF) or even pseudo-1D motion with 2DoF. Herein, magnetically steerable tubular TiO2/Fe3O4/CdS micromotors, termed microsubmarines, with 6DoF motion, based on a fuel-free design where surrounding water acts as fuel upon visible light irradiation, are presented, with an average velocity of 7.9 mu m s(-1). Besides, the generation of radicals via such water splitting aids the photocatalytic chemicals degradation with the potential to use solar radiation. A light-induced self-electrophoretic mechanism is responsible for the self-propulsion and can be used to predict the motion direction based on the structure and composition. Finally, the TiO2/Fe3O4/CdS microsubmarines are tested in a proof-of-concept application of high-energy explosive, e.g., picric acid, photocatalytic degradation, with the best performance owing to the versatility of 6DoF motion, the surface coating with amorphous TiO2 layer, and UV light. The results can help optimize light-active micromotor design for potential national security and environmental application, hydrogen evolution, and target cargo delivery.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Projekt

—

Návaznosti

O - Projekt operacniho programu

Rok uplatnění

2021

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Small

ISSN

1613-6810

e-ISSN

1613-6829

Svazek periodika

17

Číslo periodika v rámci svazku

23

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

10

Strana od-do

nestrankovano

Kód UT WoS článku

000646770600001

EID výsledku v databázi Scopus

2-s2.0-85105026981