Improved Electrochemical Performance of NTs-WS2@C Nanocomposites for Lithium-Ion and Sodium-Ion Batteries

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F22%3A43924198" target="_blank" >RIV/60461373:22310/22:43924198 - isvavai.cz</a>

Výsledek na webu

<a href="https://pubs.acs.org/doi/full/10.1021/acsami.2c06295" target="_blank" >https://pubs.acs.org/doi/full/10.1021/acsami.2c06295</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1021/acsami.2c06295" target="_blank" >10.1021/acsami.2c06295</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Improved Electrochemical Performance of NTs-WS2@C Nanocomposites for Lithium-Ion and Sodium-Ion Batteries

Popis výsledku v původním jazyce

Even though WS2nanotubes (NTs-WS2) have great potential as anode materials for lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs) thanks to their unusual layered structure, their conductivity and cycling stability are far from satisfactory. To tackle these issues, carbon-coated WS2(NTs-WS2@C) nanocomposites were prepared through a facile synthesis method that involved precipitating a carbon precursor (20% sucrose) on WS2nanotubes, followed by annealing treatment under an argon environment. Thanks to the presence of highly conductive and mechanically robust carbon on the outer surface, NTs-WS2@C nanocomposites show improved electrochemical performance compared with bare NTs-WS2. After 60 cycles at 80 mA g-1current density, the cells display high capacities of 305 mAh g-1in LIBs and 152 mAh g-1in SIBs, respectively. As the current density increases to 600 mA g-1, it provides specific capacities of 209 and 115 mAh g-1, correspondingly. The enhanced electrochemical performance in LIBs and SIBs is primarily attributed to the synergistic effects of the tubular architecture of WS2, carbon network and stable nanocomposite structure, which can effectively constrain volume variation during the metal ions intercalation/deintercalation processes. © 2022 American Chemical Society. All rights reserved.

Název v anglickém jazyce

Improved Electrochemical Performance of NTs-WS2@C Nanocomposites for Lithium-Ion and Sodium-Ion Batteries

Popis výsledku anglicky

Even though WS2nanotubes (NTs-WS2) have great potential as anode materials for lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs) thanks to their unusual layered structure, their conductivity and cycling stability are far from satisfactory. To tackle these issues, carbon-coated WS2(NTs-WS2@C) nanocomposites were prepared through a facile synthesis method that involved precipitating a carbon precursor (20% sucrose) on WS2nanotubes, followed by annealing treatment under an argon environment. Thanks to the presence of highly conductive and mechanically robust carbon on the outer surface, NTs-WS2@C nanocomposites show improved electrochemical performance compared with bare NTs-WS2. After 60 cycles at 80 mA g-1current density, the cells display high capacities of 305 mAh g-1in LIBs and 152 mAh g-1in SIBs, respectively. As the current density increases to 600 mA g-1, it provides specific capacities of 209 and 115 mAh g-1, correspondingly. The enhanced electrochemical performance in LIBs and SIBs is primarily attributed to the synergistic effects of the tubular architecture of WS2, carbon network and stable nanocomposite structure, which can effectively constrain volume variation during the metal ions intercalation/deintercalation processes. © 2022 American Chemical Society. All rights reserved.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Projekt

<a href="/cs/project/GC20-16124J" target="_blank" >GC20-16124J: Dvojdimenzionální vrstevnaté dichalkogenidy přechodných kovů / nanostrukturované uhlíkové kompozity pro aplikace na elektrochemické uchovávání energie</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2022

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

ACS Applied Materials and Interfaces

ISSN

1944-8244

e-ISSN

1944-8252

Svazek periodika

14

Číslo periodika v rámci svazku

41

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

15

Strana od-do

46386-46400

Kód UT WoS článku

000877044400001

EID výsledku v databázi Scopus

2-s2.0-85139550505