Modular assembly of a library of hybrid superlattices and artificial quantum solids

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F24%3A43929954" target="_blank" >RIV/60461373:22310/24:43929954 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/abs/pii/S2590238523006422" target="_blank" >https://www.sciencedirect.com/science/article/abs/pii/S2590238523006422</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.matt.2023.12.029" target="_blank" >10.1016/j.matt.2023.12.029</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Modular assembly of a library of hybrid superlattices and artificial quantum solids

Popis výsledku v původním jazyce

Hybrid superlattices, composed of two-dimensional atomic crystals (2DACs) and self -assembled molecular layers, provide a platform for synergizing the rich physical properties of solid-state 2DACs with customizable molecular functionalities. This study introduces a modular electrostatic co -assembly approach for synthesizing 53 distinct hybrid superlattices, using various 2DACs and molecular building blocks. Mechanistic studies reveal that the electrostatic assembly is governed by charge balance and the equilibrium between electrostatic and van der Waals interactions. Leveraging the charge balance principle, we demonstrate a precise control over the number of molecular layers and interlayer spacing by modulating the molecular charge density. Our study establishes a universal approach to a library of layered hybrid superlattices, incorporating versatile molecular functionalities into solid-state 2DACs. It promises a novel class of artificial quantum solids with designable electronic band offsets, tailored charge ordering, superconducting phase transitions, and magnetic ordering.

Název v anglickém jazyce

Modular assembly of a library of hybrid superlattices and artificial quantum solids

Popis výsledku anglicky

Hybrid superlattices, composed of two-dimensional atomic crystals (2DACs) and self -assembled molecular layers, provide a platform for synergizing the rich physical properties of solid-state 2DACs with customizable molecular functionalities. This study introduces a modular electrostatic co -assembly approach for synthesizing 53 distinct hybrid superlattices, using various 2DACs and molecular building blocks. Mechanistic studies reveal that the electrostatic assembly is governed by charge balance and the equilibrium between electrostatic and van der Waals interactions. Leveraging the charge balance principle, we demonstrate a precise control over the number of molecular layers and interlayer spacing by modulating the molecular charge density. Our study establishes a universal approach to a library of layered hybrid superlattices, incorporating versatile molecular functionalities into solid-state 2DACs. It promises a novel class of artificial quantum solids with designable electronic band offsets, tailored charge ordering, superconducting phase transitions, and magnetic ordering.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10402 - Inorganic and nuclear chemistry

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2024

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Matter

ISSN

2590-2393

e-ISSN

2590-2385

Svazek periodika

7

Číslo periodika v rámci svazku

3

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

16

Strana od-do

—

Kód UT WoS článku

001203011700001

EID výsledku v databázi Scopus

2-s2.0-85184774385