Enhancing Nitrogen Reduction Reaction through Formation of 2D/2D Hybrid Heterostructures of MoS2@rGO

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F24%3A43929965" target="_blank" >RIV/60461373:22310/24:43929965 - isvavai.cz</a>

Výsledek na webu

<a href="https://pubs.acs.org/doi/full/10.1021/acsami.4c00719" target="_blank" >https://pubs.acs.org/doi/full/10.1021/acsami.4c00719</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1021/acsami.4c00719" target="_blank" >10.1021/acsami.4c00719</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Enhancing Nitrogen Reduction Reaction through Formation of 2D/2D Hybrid Heterostructures of MoS2@rGO

Popis výsledku v původním jazyce

Given the challenging task of constructing an efficient nitrogen reduction reaction (NRR) electrocatalyst with enhanced ambient condition performance, properties such as high specific surface area, fast electron transfer, and design of the catalyst surface constitute a group of key factors to be taken into consideration to guarantee outstanding catalytic performance and durability. Thereof, this work investigates the contribution of the 2D/2D heterojunction interface between MoS2 and reduced graphene oxide (rGO) on the electrocatalytic synthesis of NH3 in an alkaline media. The results revealed remarkable NRR performance on the MoS2@rGO 2D/2D hybrid electrocatalyst, characterized by a high NRR sensitivity (faradaic efficiency) of 34.7% with an NH3 yield rate of 3.98 +/- 0.19 mg h(-1) cm(-2) at an overpotential of -0.3 V vs RHE in 0.1 M KOH solution. The hybrid electrocatalysts also exhibited selectivity for NH3 synthesis against the production of the hydrazine (N2H4) byproduct, hindrance of the competitive hydrogen evolution reaction (HER), and good durability over an operation period of 8 h. In hindsight, the study presented a low-cost and highly efficient catalyst design for achieving enhanced ammonia synthesis in alkaline media via the formation of defect-rich ultrathin MoS2@rGO nanostructures, consisting predominantly of an HER-hindering hexagonal 2H-MoS2 phase.

Název v anglickém jazyce

Enhancing Nitrogen Reduction Reaction through Formation of 2D/2D Hybrid Heterostructures of MoS2@rGO

Popis výsledku anglicky

Given the challenging task of constructing an efficient nitrogen reduction reaction (NRR) electrocatalyst with enhanced ambient condition performance, properties such as high specific surface area, fast electron transfer, and design of the catalyst surface constitute a group of key factors to be taken into consideration to guarantee outstanding catalytic performance and durability. Thereof, this work investigates the contribution of the 2D/2D heterojunction interface between MoS2 and reduced graphene oxide (rGO) on the electrocatalytic synthesis of NH3 in an alkaline media. The results revealed remarkable NRR performance on the MoS2@rGO 2D/2D hybrid electrocatalyst, characterized by a high NRR sensitivity (faradaic efficiency) of 34.7% with an NH3 yield rate of 3.98 +/- 0.19 mg h(-1) cm(-2) at an overpotential of -0.3 V vs RHE in 0.1 M KOH solution. The hybrid electrocatalysts also exhibited selectivity for NH3 synthesis against the production of the hydrazine (N2H4) byproduct, hindrance of the competitive hydrogen evolution reaction (HER), and good durability over an operation period of 8 h. In hindsight, the study presented a low-cost and highly efficient catalyst design for achieving enhanced ammonia synthesis in alkaline media via the formation of defect-rich ultrathin MoS2@rGO nanostructures, consisting predominantly of an HER-hindering hexagonal 2H-MoS2 phase.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Projekt

<a href="/cs/project/LL2101" target="_blank" >LL2101: Příští Generace Monoelementárních 2D Materiálů</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2024

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

ACS Applied Materials &amp; Interfaces

ISSN

1944-8244

e-ISSN

1944-8252

Svazek periodika

16

Číslo periodika v rámci svazku

19

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

11

Strana od-do

24514-24524

Kód UT WoS článku

001227820000001

EID výsledku v databázi Scopus

2-s2.0-85192182878