Searching for a cost‑effective method of determining sorption properties for the industrial use of CO2 capture

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22320%2F23%3A43926214" target="_blank" >RIV/60461373:22320/23:43926214 - isvavai.cz</a>

Výsledek na webu

<a href="https://link.springer.com/content/pdf/10.1007/s11696-023-02933-x.pdf" target="_blank" >https://link.springer.com/content/pdf/10.1007/s11696-023-02933-x.pdf</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1007/s11696-023-02933-x" target="_blank" >10.1007/s11696-023-02933-x</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Searching for a cost‑effective method of determining sorption properties for the industrial use of CO2 capture

Popis výsledku v původním jazyce

The study focuses on laboratory testing of carbon-dioxide adsorption. It compares three methods used to determine the capacity of the adsorbents proposed for CO2 capture. The tests have been performed on two samples, namely natural clinoptilolite and a 13X molecular sieve. Two methods were dynamic and one was static. The first dynamic method evaluated the capacity based on the change in CO2 volume fraction before and after a fixed-bed adsorber. For the same purpose, the second dynamic method used a gravimetric procedure. The static method detected a change in pressure during CO2 adsorption. The capacities determined for carbon-dioxide mole fractions of 5, 10, 13 and 20% at temperatures of 30 and 40 °C at atmospheric pressure were compared. The apparatus with a fixed-bed adsorber made it possible to perform tests also for overpressures of 2 and 5 bar and lower temperatures. The capacity obtained on the three apparatuses showed good agreement. The maximum capacity (3.32 mmol g−1) was determined for the 13X sample at 10 °C and a partial CO2 pressure of 120 kPa and, conversely, the lowest (0.12 mmol g−1) for clinoptilolite at 40 °C and a partial CO2 pressure of 5 kPa. There was no significant difference in capacity standard deviations between the apparatus (0.014–0.036 mmol g−1). The fixed-bed apparatus required one to three orders of magnitude more gas for the experiment and was more challenging to operate and evaluate the data.

Název v anglickém jazyce

Searching for a cost‑effective method of determining sorption properties for the industrial use of CO2 capture

Popis výsledku anglicky

The study focuses on laboratory testing of carbon-dioxide adsorption. It compares three methods used to determine the capacity of the adsorbents proposed for CO2 capture. The tests have been performed on two samples, namely natural clinoptilolite and a 13X molecular sieve. Two methods were dynamic and one was static. The first dynamic method evaluated the capacity based on the change in CO2 volume fraction before and after a fixed-bed adsorber. For the same purpose, the second dynamic method used a gravimetric procedure. The static method detected a change in pressure during CO2 adsorption. The capacities determined for carbon-dioxide mole fractions of 5, 10, 13 and 20% at temperatures of 30 and 40 °C at atmospheric pressure were compared. The apparatus with a fixed-bed adsorber made it possible to perform tests also for overpressures of 2 and 5 bar and lower temperatures. The capacity obtained on the three apparatuses showed good agreement. The maximum capacity (3.32 mmol g−1) was determined for the 13X sample at 10 °C and a partial CO2 pressure of 120 kPa and, conversely, the lowest (0.12 mmol g−1) for clinoptilolite at 40 °C and a partial CO2 pressure of 5 kPa. There was no significant difference in capacity standard deviations between the apparatus (0.014–0.036 mmol g−1). The fixed-bed apparatus required one to three orders of magnitude more gas for the experiment and was more challenging to operate and evaluate the data.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

20704 - Energy and fuels

Projekt

<a href="/cs/project/TK03030167" target="_blank" >TK03030167: Nízkoemisní technologie energetického využití biomasy a alternativních paliv</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Chemical Papers

ISSN

0366-6352

e-ISSN

2585-7290

Svazek periodika

77

Číslo periodika v rámci svazku

26 June 2023

Stát vydavatele periodika

CH - Švýcarská konfederace

Počet stran výsledku

17

Strana od-do

"6217–6233"

Kód UT WoS článku

001013417800002

EID výsledku v databázi Scopus

2-s2.0-85162975668