Coupling Reactions of alpha-Bromocarboxylate with Non-Aromatic N-Heterocycles

Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22330%2F09%3A00022304" target="_blank" >RIV/60461373:22330/09:00022304 - isvavai.cz</a>
Výsledek na webu
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DOI - Digital Object Identifier
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Jazyk výsledku
angličtina
Název v původním jazyce
Coupling Reactions of alpha-Bromocarboxylate with Non-Aromatic N-Heterocycles
Popis výsledku v původním jazyce
The conditions for the C-N bond forming reaction (C-N coupling reaction) between alpha-bromocarboxylate and nitrogen-containing non-aromatic heterocyclic rings under heterogeneous copper(I) oxide catalysis are investigated in this paper. All the generated compounds were fully characterized by IR, NMR and MS spectroscopy. Ab initio/DFT calculations of partial charges on nitrogen atoms in all the discussed heterocycles and on C-(2) of carboxylate under applied conditions were predicted. These in silico results correlate relatively with the experimental observations.
Název v anglickém jazyce
Coupling Reactions of alpha-Bromocarboxylate with Non-Aromatic N-Heterocycles
Popis výsledku anglicky
The conditions for the C-N bond forming reaction (C-N coupling reaction) between alpha-bromocarboxylate and nitrogen-containing non-aromatic heterocyclic rings under heterogeneous copper(I) oxide catalysis are investigated in this paper. All the generated compounds were fully characterized by IR, NMR and MS spectroscopy. Ab initio/DFT calculations of partial charges on nitrogen atoms in all the discussed heterocycles and on C-(2) of carboxylate under applied conditions were predicted. These in silico results correlate relatively with the experimental observations.

Druh
J<sub>x</sub> - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
CEP obor
CC - Organická chemie
OECD FORD obor
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Rok uplatnění
2009
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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