Smíšené oscilace v pH-oscilátoru

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F06%3A00016829" target="_blank" >RIV/60461373:22340/06:00016829 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Complex dynamics of oxidation of thiosulphate by hydrogen peroxide catalyzed by cupric ions

Popis výsledku v původním jazyce

The oxidation of thiosulphate by hydrogen peroxide catalyzed by cupric ions in acidic solution of sulphuric acid (HPTCu reaction) is studied. The reaction exhibits large variety of nonlinear dynamical behaviour (oscillations, bistability and excitability). This reaction belongs to the group of so-called pH-oscillators, because of significant changes in the pH value in time. To explain such complex nonlinear behaviour, the mechanism of the reaction is needed. To improve existing mechanistic model1 more experimental date are needed. In this paper the experimental study of the HPTCu reaction is presented. It is known, that HPTCu reactions exhibits different types of oscillations. But no detailed study of oscillatory regimes has been published except for work of Orbán and Epstein2. Therefore the focus of this contribution is on oscillatory behaviour of the HPTCu reaction carried out in a continuous stirred tank reactor (CSTR) at constant temperature. The pH time series are measured. The re

Název v anglickém jazyce

Complex dynamics of oxidation of thiosulphate by hydrogen peroxide catalyzed by cupric ions

Popis výsledku anglicky

The oxidation of thiosulphate by hydrogen peroxide catalyzed by cupric ions in acidic solution of sulphuric acid (HPTCu reaction) is studied. The reaction exhibits large variety of nonlinear dynamical behaviour (oscillations, bistability and excitability). This reaction belongs to the group of so-called pH-oscillators, because of significant changes in the pH value in time. To explain such complex nonlinear behaviour, the mechanism of the reaction is needed. To improve existing mechanistic model1 more experimental date are needed. In this paper the experimental study of the HPTCu reaction is presented. It is known, that HPTCu reactions exhibits different types of oscillations. But no detailed study of oscillatory regimes has been published except for work of Orbán and Epstein2. Therefore the focus of this contribution is on oscillatory behaviour of the HPTCu reaction carried out in a continuous stirred tank reactor (CSTR) at constant temperature. The pH time series are measured. The re

Druh

D - Stať ve sborníku

CEP obor

CI - Průmyslová chemie a chemické inženýrství

OECD FORD obor

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Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2006

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název statě ve sborníku

Proceedings of 33rd International Conference of SSCHE

ISBN

80-227-2409-2

ISSN

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e-ISSN

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Počet stran výsledku

8

Strana od-do

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Název nakladatele

Slovak University of Technology

Místo vydání

Bratislava

Místo konání akce

Tatranské Matliáre

Datum konání akce

22. 5. 2006

Typ akce podle státní příslušnosti

WRD - Celosvětová akce

Kód UT WoS článku

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