Interactions of Volatile Organic Compounds with the Ionic Liquid 1-Butyl-1-methylpyrrolidinium Dicyanamide
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F11%3A43891415" target="_blank" >RIV/60461373:22340/11:43891415 - isvavai.cz</a>
Výsledek na webu
<a href="http://dx.doi.org/10.1021/je200822w" target="_blank" >http://dx.doi.org/10.1021/je200822w</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/je200822w" target="_blank" >10.1021/je200822w</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Interactions of Volatile Organic Compounds with the Ionic Liquid 1-Butyl-1-methylpyrrolidinium Dicyanamide
Popis výsledku v původním jazyce
Interactions of volatile organic compounds with the ionic liquid (IL) 1-butyl-1-methylpyrrolidinium dicyanamide [BMPYR][DCA] were explored through systematic gas?liquid chromatography retention measurements. Infinite dilution activity coefficients and gas?liquid partition coefficients KL of 30 selected hydrocarbons, alcohols, ketones, ethers, esters, haloalkanes, nitrogen- and sulfur-containing compounds in [BMPYR][DCA] were determined at five temperatures in the range from (318.15 to 353.15) K. Partialmolar excess enthalpies and entropies at infinite dilution were derived from the temperature dependence of the infinite dilution activity coefficient values. The Linear Free Energy Relationship (LFER) solvation model was used to correlate successfully the KL values. The LFER correlation parameters and excess thermodynamic functions were analyzed to disclose molecular interactions operating between the IL and the individual solutes. Among other ILs, [BMPYR][DCA] was identified to be a fa
Název v anglickém jazyce
Interactions of Volatile Organic Compounds with the Ionic Liquid 1-Butyl-1-methylpyrrolidinium Dicyanamide
Popis výsledku anglicky
Interactions of volatile organic compounds with the ionic liquid (IL) 1-butyl-1-methylpyrrolidinium dicyanamide [BMPYR][DCA] were explored through systematic gas?liquid chromatography retention measurements. Infinite dilution activity coefficients and gas?liquid partition coefficients KL of 30 selected hydrocarbons, alcohols, ketones, ethers, esters, haloalkanes, nitrogen- and sulfur-containing compounds in [BMPYR][DCA] were determined at five temperatures in the range from (318.15 to 353.15) K. Partialmolar excess enthalpies and entropies at infinite dilution were derived from the temperature dependence of the infinite dilution activity coefficient values. The Linear Free Energy Relationship (LFER) solvation model was used to correlate successfully the KL values. The LFER correlation parameters and excess thermodynamic functions were analyzed to disclose molecular interactions operating between the IL and the individual solutes. Among other ILs, [BMPYR][DCA] was identified to be a fa
Klasifikace
Druh
J<sub>x</sub> - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)
CEP obor
CF - Fyzikální chemie a teoretická chemie
OECD FORD obor
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Návaznosti výsledku
Projekt
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Návaznosti
Z - Vyzkumny zamer (s odkazem do CEZ)
Ostatní
Rok uplatnění
2011
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Journal of Chemical Engineering Data
ISSN
0021-9568
e-ISSN
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Svazek periodika
56
Číslo periodika v rámci svazku
12
Stát vydavatele periodika
US - Spojené státy americké
Počet stran výsledku
10
Strana od-do
4909-4918
Kód UT WoS článku
000297608800087
EID výsledku v databázi Scopus
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