Contribution to cation-pi interaction of the univalent silver cation with racemic [7]helicene in the solid state

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F17%3A43903848" target="_blank" >RIV/60461373:22340/17:43903848 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/60460709:41330/17:74570 RIV/67985858:_____/17:00507129

Výsledek na webu

<a href="https://link.springer.com/article/10.1007%2Fs11224-015-0679-4" target="_blank" >https://link.springer.com/article/10.1007%2Fs11224-015-0679-4</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1007/s11224-015-0679-4" target="_blank" >10.1007/s11224-015-0679-4</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Contribution to cation-pi interaction of the univalent silver cation with racemic [7]helicene in the solid state

Popis výsledku v původním jazyce

Yellow crystals of the complex [7]helicene-silver perchlorate (i.e., C30H18-AgClO4 or more accurately [Ag(eta(4)-C30H18)]ClO4, respectively), crystallizing in the monoclinic system with the centrosymmetric P2(1)/c space group, where a = 14.4230(3) , b = 10.2804(3) , c = 15.2541(4) , and beta = 91.856(2)A degrees, were prepared by slow evaporation of the solvent from a solution obtained by mixing equimolecular amounts of racemic [7]helicene and silver perchlorate in toluene at ambient temperature. Characteristic feature of the complex packing in the solid state is the formation of infinite antiparallel layers of dimeric structures of the proven complex. The investigated [7]helicene ligand in the racemic form functions as a molecular tweezer for the univalent silver cation.

Název v anglickém jazyce

Contribution to cation-pi interaction of the univalent silver cation with racemic [7]helicene in the solid state

Popis výsledku anglicky

Yellow crystals of the complex [7]helicene-silver perchlorate (i.e., C30H18-AgClO4 or more accurately [Ag(eta(4)-C30H18)]ClO4, respectively), crystallizing in the monoclinic system with the centrosymmetric P2(1)/c space group, where a = 14.4230(3) , b = 10.2804(3) , c = 15.2541(4) , and beta = 91.856(2)A degrees, were prepared by slow evaporation of the solvent from a solution obtained by mixing equimolecular amounts of racemic [7]helicene and silver perchlorate in toluene at ambient temperature. Characteristic feature of the complex packing in the solid state is the formation of infinite antiparallel layers of dimeric structures of the proven complex. The investigated [7]helicene ligand in the racemic form functions as a molecular tweezer for the univalent silver cation.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10406 - Analytical chemistry

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2017

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Structural Chemistry

ISSN

1040-0400

e-ISSN

—

Svazek periodika

28

Číslo periodika v rámci svazku

3

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

5

Strana od-do

873-877

Kód UT WoS článku

000400574100031

EID výsledku v databázi Scopus

2-s2.0-85018728533