Vapor?Liquid Equilibria for Binary Mixtures of Methyl Nonafluorobutyl Ether + Acetone, Cyclopentyl Methyl Ether, Ethyl Acetate, n-Heptane, Methanol, and Toluene.ne, Cyclopentyl Methyl Ether, Ethyl Acetate, n-Heptane, Methanol, and Toluene
Identifikátory výsledku
Kód výsledku v IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F17%3A43913487" target="_blank" >RIV/60461373:22340/17:43913487 - isvavai.cz</a>
Výsledek na webu
<a href="http://dx.doi.org/10.1021/acs.jced.7b00599" target="_blank" >http://dx.doi.org/10.1021/acs.jced.7b00599</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.jced.7b00599" target="_blank" >10.1021/acs.jced.7b00599</a>
Alternativní jazyky
Jazyk výsledku
angličtina
Název v původním jazyce
Vapor?Liquid Equilibria for Binary Mixtures of Methyl Nonafluorobutyl Ether + Acetone, Cyclopentyl Methyl Ether, Ethyl Acetate, n-Heptane, Methanol, and Toluene.ne, Cyclopentyl Methyl Ether, Ethyl Acetate, n-Heptane, Methanol, and Toluene
Popis výsledku v původním jazyce
Measurements of vapor-liquid equilibrium data in binary systems methyl nonafluorobutyl ether + solvent (acetone, cyclopentyl methyl ether, ethyl acetate, n-heptane, methanol, and toluene) were carried out at constant temperature (328.15 or 318.15 K) by means of a vapor-liquid equilibrium circulation still. In the most cases, the acquired data satisfied thermodynamic consistency tests. The obtained vapor-liquid equilibrium data were (successfully) correlated by two principally different thermodynamic models: the nonrandom two-liquid equation for the excess Gibbs energy, and the perturbed-chain statistical associating fluid theory equation of state. The latter model was tested also for its predictive capabilities and was found not to be suitable for reliable predictions in the studied binary systems, although it may correctly predict the azeotropic behavior of some systems.
Název v anglickém jazyce
Vapor?Liquid Equilibria for Binary Mixtures of Methyl Nonafluorobutyl Ether + Acetone, Cyclopentyl Methyl Ether, Ethyl Acetate, n-Heptane, Methanol, and Toluene.ne, Cyclopentyl Methyl Ether, Ethyl Acetate, n-Heptane, Methanol, and Toluene
Popis výsledku anglicky
Measurements of vapor-liquid equilibrium data in binary systems methyl nonafluorobutyl ether + solvent (acetone, cyclopentyl methyl ether, ethyl acetate, n-heptane, methanol, and toluene) were carried out at constant temperature (328.15 or 318.15 K) by means of a vapor-liquid equilibrium circulation still. In the most cases, the acquired data satisfied thermodynamic consistency tests. The obtained vapor-liquid equilibrium data were (successfully) correlated by two principally different thermodynamic models: the nonrandom two-liquid equation for the excess Gibbs energy, and the perturbed-chain statistical associating fluid theory equation of state. The latter model was tested also for its predictive capabilities and was found not to be suitable for reliable predictions in the studied binary systems, although it may correctly predict the azeotropic behavior of some systems.
Klasifikace
Druh
J<sub>imp</sub> - Článek v periodiku v databázi Web of Science
CEP obor
—
OECD FORD obor
10403 - Physical chemistry
Návaznosti výsledku
Projekt
—
Návaznosti
S - Specificky vyzkum na vysokych skolach
Ostatní
Rok uplatnění
2017
Kód důvěrnosti údajů
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Údaje specifické pro druh výsledku
Název periodika
Journal of Chemical Engineering Data
ISSN
0021-9568
e-ISSN
—
Svazek periodika
62
Číslo periodika v rámci svazku
11
Stát vydavatele periodika
US - Spojené státy americké
Počet stran výsledku
11
Strana od-do
3878-3888
Kód UT WoS článku
000415140900026
EID výsledku v databázi Scopus
2-s2.0-85033551032