Rotational spectra of hydrazoic acid

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F17%3A43915173" target="_blank" >RIV/60461373:22340/17:43915173 - isvavai.cz</a>

Výsledek na webu

<a href="https://ac.els-cdn.com/S0022285217300036/1-s2.0-S0022285217300036-main.pdf?_tid=spdf-94882c3d-cc81-4bbd-8270-1014376b8331&acdnat=1519811185_7d79dae62e8d59349b32340136b28fb5" target="_blank" >https://ac.els-cdn.com/S0022285217300036/1-s2.0-S0022285217300036-main.pdf?_tid=spdf-94882c3d-cc81-4bbd-8270-1014376b8331&acdnat=1519811185_7d79dae62e8d59349b32340136b28fb5</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jms.2017.04.002" target="_blank" >10.1016/j.jms.2017.04.002</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Rotational spectra of hydrazoic acid

Popis výsledku v původním jazyce

Hydrazoic acid is a quasi-linear molecule with typical strong perturbations among rotational levels in different vibrationally excited states. The rovibrational interactions among the ground and the two lowest vibrationally excited states v(5) and v(6) make the line assignments very complicated. Overall 446 new rotational transitions were measured and assigned to rovibrational quantum numbers. This new dataset contains 194 transitions from the ground state, 160 and 92 transitions from the vibrationally excited v(s) and v(6) states, respectively. The rotational data set is extended up to K-a = 8 for the ground state, K-a = 7 for v(5), and Ka = 3 for vs. The frequencies of these new rotational lines, along with the data from previous sub millimetre and infrared studies were quantitatively analysed. The level crossings among ground and vibrationally excited v(5) and v(6) states and the corresponding rovibrational interactions were described in detail. (C) 2017 Elsevier Inc. All rights reserved.

Název v anglickém jazyce

Rotational spectra of hydrazoic acid

Popis výsledku anglicky

Hydrazoic acid is a quasi-linear molecule with typical strong perturbations among rotational levels in different vibrationally excited states. The rovibrational interactions among the ground and the two lowest vibrationally excited states v(5) and v(6) make the line assignments very complicated. Overall 446 new rotational transitions were measured and assigned to rovibrational quantum numbers. This new dataset contains 194 transitions from the ground state, 160 and 92 transitions from the vibrationally excited v(s) and v(6) states, respectively. The rotational data set is extended up to K-a = 8 for the ground state, K-a = 7 for v(5), and Ka = 3 for vs. The frequencies of these new rotational lines, along with the data from previous sub millimetre and infrared studies were quantitatively analysed. The level crossings among ground and vibrationally excited v(5) and v(6) states and the corresponding rovibrational interactions were described in detail. (C) 2017 Elsevier Inc. All rights reserved.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10406 - Analytical chemistry

Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2017

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Molecular Structure

ISSN

0022-2860

e-ISSN

—

Svazek periodika

337

Číslo periodika v rámci svazku

Neuvedeno

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

5

Strana od-do

27-31

Kód UT WoS článku

000405760800005

EID výsledku v databázi Scopus

2-s2.0-85017515417