Vapor pressures and thermophysical properties of selected monoterpenoids II

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F23%3A43927752" target="_blank" >RIV/60461373:22340/23:43927752 - isvavai.cz</a>

Výsledek na webu

<a href="https://www.sciencedirect.com/science/article/pii/S0378381222003235" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0378381222003235</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.fluid.2022.113704" target="_blank" >10.1016/j.fluid.2022.113704</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Vapor pressures and thermophysical properties of selected monoterpenoids II

Popis výsledku v původním jazyce

In this work, a thermodynamic study of four enantiopure terpenoids, myrtenal, myrtenol, α-terpineol, and trans-sobrerol is presented. Vapor pressures of the selected terpenoids were determined using two static apparatus in a combined temperature range from 248 to 363 K. Heat capacities of the samples were determined by Tian-Calvet calorimetry in the temperature range from 261 to 353 K. Phase behaviour (melting temperature, fusion enthalpy, crystallization temperature, and potential polymorphic transformations) were studied using heat-flux calorimetry. Using a combination of quantum-chemical calculations and statistical thermodynamics, ideal-gas heat capacities and entropies were determined. Finally, consistency of the phase behaviour, vapor pressure, and heat capacity experimental data with the theoretically calculated data was assessed using the method of simultaneous correlation. © 2022 Elsevier B.V.

Název v anglickém jazyce

Vapor pressures and thermophysical properties of selected monoterpenoids II

Popis výsledku anglicky

In this work, a thermodynamic study of four enantiopure terpenoids, myrtenal, myrtenol, α-terpineol, and trans-sobrerol is presented. Vapor pressures of the selected terpenoids were determined using two static apparatus in a combined temperature range from 248 to 363 K. Heat capacities of the samples were determined by Tian-Calvet calorimetry in the temperature range from 261 to 353 K. Phase behaviour (melting temperature, fusion enthalpy, crystallization temperature, and potential polymorphic transformations) were studied using heat-flux calorimetry. Using a combination of quantum-chemical calculations and statistical thermodynamics, ideal-gas heat capacities and entropies were determined. Finally, consistency of the phase behaviour, vapor pressure, and heat capacity experimental data with the theoretically calculated data was assessed using the method of simultaneous correlation. © 2022 Elsevier B.V.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10403 - Physical chemistry

Projekt

<a href="/cs/project/GA22-07164S" target="_blank" >GA22-07164S: Racionální návrh systémů pro dodávání léčiv založených na laditelných biodegradabilních polymerech: iterativní in silico a experimentální postup</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

FLUID PHASE EQUILIBRIA

ISSN

0378-3812

e-ISSN

1879-0224

Svazek periodika

567

Číslo periodika v rámci svazku

duben

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

12

Strana od-do

—

Kód UT WoS článku

000910622600001

EID výsledku v databázi Scopus

2-s2.0-85144604829