Carbonized Leather Waste with Deposited Polypyrrole Nanotubes: Conductivity and Dye Adsorption

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22810%2F23%3A43930175" target="_blank" >RIV/60461373:22810/23:43930175 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/00216208:11320/23:10473999 RIV/70883521:28610/23:63569798

Výsledek na webu

<a href="https://www.scopus.com/record/display.uri?eid=2-s2.0-85175079918&origin=resultslist&sort=plf-f&src=s&sot=b&sdt=b&s=DOI%2810.3390%2Fnano13202794%29&sessionSearchId=dfd36e77a16739c73abb14811cf0973c&relpos=0" target="_blank" >https://www.scopus.com/record/display.uri?eid=2-s2.0-85175079918&origin=resultslist&sort=plf-f&src=s&sot=b&sdt=b&s=DOI%2810.3390%2Fnano13202794%29&sessionSearchId=dfd36e77a16739c73abb14811cf0973c&relpos=0</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/nano13202794" target="_blank" >10.3390/nano13202794</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Carbonized Leather Waste with Deposited Polypyrrole Nanotubes: Conductivity and Dye Adsorption

Popis výsledku v původním jazyce

This paper reports the conversion of a waste to a conducting material, exploiting the ability to adsorb pollutant organic dyes. Leather waste was carbonized at 800 °C in an inert nitrogen atmosphere. The resulting biochar was used for in-situ deposition of polypyrrole nanotubes produced by the oxidative polymerization of pyrrole in the presence of methyl orange. The composites of carbonized leather with deposited polypyrrole nanotubes of various composition were compared with similar composites based on globular polypyrrole. Their molecular structure was characterized by infrared and Raman spectra. Both conducting components formed a bicontinuous structure. The resistivity was newly determined by a four-point van der Pauw method and monitored as a function of pressure applied up to 10 MPa. The typical conductivity of composites was of the order of 0.1 to 1 S cm−1 and it was always higher for polypyrrole nanotubes than for globular polypyrrole. The method also allows for the assessment of mechanical features, such as powder fluffiness. The conductivity decreased by 1–2 orders of magnitude after treatment with ammonia but still maintained a level acceptable for applications operating under non-acidic conditions. The composites were tested for dye adsorption, specifically cationic methylene blue and anionic methyl orange, using UV-vis spectroscopy. The composites were designed for future use as functional adsorbents controlled by the electrical potential or organic electrode materials. © 2023 by the authors.

Název v anglickém jazyce

Carbonized Leather Waste with Deposited Polypyrrole Nanotubes: Conductivity and Dye Adsorption

Popis výsledku anglicky

This paper reports the conversion of a waste to a conducting material, exploiting the ability to adsorb pollutant organic dyes. Leather waste was carbonized at 800 °C in an inert nitrogen atmosphere. The resulting biochar was used for in-situ deposition of polypyrrole nanotubes produced by the oxidative polymerization of pyrrole in the presence of methyl orange. The composites of carbonized leather with deposited polypyrrole nanotubes of various composition were compared with similar composites based on globular polypyrrole. Their molecular structure was characterized by infrared and Raman spectra. Both conducting components formed a bicontinuous structure. The resistivity was newly determined by a four-point van der Pauw method and monitored as a function of pressure applied up to 10 MPa. The typical conductivity of composites was of the order of 0.1 to 1 S cm−1 and it was always higher for polypyrrole nanotubes than for globular polypyrrole. The method also allows for the assessment of mechanical features, such as powder fluffiness. The conductivity decreased by 1–2 orders of magnitude after treatment with ammonia but still maintained a level acceptable for applications operating under non-acidic conditions. The composites were tested for dye adsorption, specifically cationic methylene blue and anionic methyl orange, using UV-vis spectroscopy. The composites were designed for future use as functional adsorbents controlled by the electrical potential or organic electrode materials. © 2023 by the authors.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10404 - Polymer science

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2023

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Nanomaterials

ISSN

2079-4991

e-ISSN

2079-4991

Svazek periodika

13

Číslo periodika v rámci svazku

20

Stát vydavatele periodika

LT - Litevská republika

Počet stran výsledku

14

Strana od-do

2794-2818

Kód UT WoS článku

001089712900001

EID výsledku v databázi Scopus

2-s2.0-85175079918