Electroreduction of Methyl Azinyl Ketoximes and Their Ni(II), Cu(II), and Zn(II) Complexes on Mercury - Correlation with Their Hydrolytic Activity.

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F02%3A54020201" target="_blank" >RIV/61388955:_____/02:54020201 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Electroreduction of Methyl Azinyl Ketoximes and Their Ni(II), Cu(II), and Zn(II) Complexes on Mercury - Correlation with Their Hydrolytic Activity.

Popis výsledku v původním jazyce

Ketoximes and their metal chelate complexes are both active as catalysts in hydrolysis of esters. Electroreduction of five azinylmethylketoximes I-V and their Ni(II), Cu(II) and Zn(II) complexes was investigated polarographically and correlated with acidity of hydroxyimino group, nucleophilicity of dissociated oximate anion and with hydrolytic activity towards model substrate (p-nitrophenylacetate). Three different types of reduction of chelates were observed and their influence on the catalytic activity discussed.

Název v anglickém jazyce

Electroreduction of Methyl Azinyl Ketoximes and Their Ni(II), Cu(II), and Zn(II) Complexes on Mercury - Correlation with Their Hydrolytic Activity.

Popis výsledku anglicky

Ketoximes and their metal chelate complexes are both active as catalysts in hydrolysis of esters. Electroreduction of five azinylmethylketoximes I-V and their Ni(II), Cu(II) and Zn(II) complexes was investigated polarographically and correlated with acidity of hydroxyimino group, nucleophilicity of dissociated oximate anion and with hydrolytic activity towards model substrate (p-nitrophenylacetate). Three different types of reduction of chelates were observed and their influence on the catalytic activity discussed.

Druh

C - Kapitola v odborné knize

CEP obor

CF - Fyzikální chemie a teoretická chemie

OECD FORD obor

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Projekt

<a href="/cs/project/GA203%2F01%2F1093" target="_blank" >GA203/01/1093: Vliv elektronové distribuce na reaktivitu oximů vůči esterům</a><br>

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2002

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název knihy nebo sborníku

Organic Electrochemistry.

ISBN

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Počet stran výsledku

5

Strana od-do

142-146

Počet stran knihy

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Název nakladatele

ECS

Místo vydání

Pennington

Kód UT WoS kapitoly

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