Disproporcionace trimethyl benzenů na širokoporézníích zeolitech: katalytická a adsorpční studie

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F04%3A00000309" target="_blank" >RIV/61388955:_____/04:00000309 - isvavai.cz</a>

Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Disproportionation of Trimethyl Benzenes over Large Pore Zeolites: Catalytic and Adsorption Study

Popis výsledku v původním jazyce

The effect of the structure of large pore zeolites of Mordenite, beta, L and Y types on the activity, selectivity to xylenes and time-on-stream stability was investigated in trimethyl benzene disproportionation. Significant differences in conversion andtime-on-stream stability were observed among individual zeolites. Zeolite beta and zeolite Y were found to exhibit the highest stability in conversion of trimethyl benzenes, while zeolite L and Mordenite were deactivated much faster. The optimum reactionconditions to achieve a high and stable conversion with sufficient selectivity to xylenes were at the reaction temperature of 400 degreesC with WHSV = 5-20 h(-1). Diffusion coefficients of trimethyl and tetramethyl benzenes over zeolites Y, beta and Mordenite at 25 degreesC were determined. Due to the significant differences in diffusion of individual trimethyl and tetramethyl benzenes, it is expected that diffusion of these molecules substantially influence the rate of this reaction.

Název v anglickém jazyce

Disproportionation of Trimethyl Benzenes over Large Pore Zeolites: Catalytic and Adsorption Study

Popis výsledku anglicky

The effect of the structure of large pore zeolites of Mordenite, beta, L and Y types on the activity, selectivity to xylenes and time-on-stream stability was investigated in trimethyl benzene disproportionation. Significant differences in conversion andtime-on-stream stability were observed among individual zeolites. Zeolite beta and zeolite Y were found to exhibit the highest stability in conversion of trimethyl benzenes, while zeolite L and Mordenite were deactivated much faster. The optimum reactionconditions to achieve a high and stable conversion with sufficient selectivity to xylenes were at the reaction temperature of 400 degreesC with WHSV = 5-20 h(-1). Diffusion coefficients of trimethyl and tetramethyl benzenes over zeolites Y, beta and Mordenite at 25 degreesC were determined. Due to the significant differences in diffusion of individual trimethyl and tetramethyl benzenes, it is expected that diffusion of these molecules substantially influence the rate of this reaction.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CF - Fyzikální chemie a teoretická chemie

OECD FORD obor

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Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2004

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Applied Catalysis

ISSN

0926-860X

e-ISSN

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Svazek periodika

277

Číslo periodika v rámci svazku

1/2

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

9

Strana od-do

191-199

Kód UT WoS článku

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EID výsledku v databázi Scopus

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