Catalysis by Mesoporous Molecular Sieves

Kód výsledku v IS VaVaI

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Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Catalysis by Mesoporous Molecular Sieves

Popis výsledku v původním jazyce

Mesoporous molecular sieves of various chemical composition, structural types, and dimensionality of their channels are interesting ordered materials with a high potential in adsorption but particularly in catalysis. This review covers various aspects ofthe catalytic behavior of mesoporous molecular sieves, in which these mesoporous molecular sieves operate both as catalysts or as catalyst supports for highly active oxidic or organometallic species. In the first part, examples of catalytic mesoporous molecular sieves are focused on single heteroatoms located in siliceous matrix as active sites for acid-catalyzed reactions, oxidation with hydrogen peroxide by Baeyer-Villiger reaction, Meerwein-Ponndorf-Verley reduction, esterification, and etherification. The second part describes catalytic systems based on mesoporous silica or alumina supports modified with transition metal oxides for hydrodesulfurization (MoO3) and metathesis of olefins and unsaturated esters (MoO3 or Re2O7).

Název v anglickém jazyce

Catalysis by Mesoporous Molecular Sieves

Popis výsledku anglicky

Mesoporous molecular sieves of various chemical composition, structural types, and dimensionality of their channels are interesting ordered materials with a high potential in adsorption but particularly in catalysis. This review covers various aspects ofthe catalytic behavior of mesoporous molecular sieves, in which these mesoporous molecular sieves operate both as catalysts or as catalyst supports for highly active oxidic or organometallic species. In the first part, examples of catalytic mesoporous molecular sieves are focused on single heteroatoms located in siliceous matrix as active sites for acid-catalyzed reactions, oxidation with hydrogen peroxide by Baeyer-Villiger reaction, Meerwein-Ponndorf-Verley reduction, esterification, and etherification. The second part describes catalytic systems based on mesoporous silica or alumina supports modified with transition metal oxides for hydrodesulfurization (MoO3) and metathesis of olefins and unsaturated esters (MoO3 or Re2O7).

Druh

C - Kapitola v odborné knize

CEP obor

CF - Fyzikální chemie a teoretická chemie

OECD FORD obor

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Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2009

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název knihy nebo sborníku

Ordered Porous Solids - Recent Advances and Prospects

ISBN

978-0-444-53189-6

Počet stran výsledku

19

Strana od-do

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Počet stran knihy

788

Název nakladatele

Elsevier B.V./Ltd

Místo vydání

Oxford

Kód UT WoS kapitoly

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