Photodissociation of Molecules in Hydrogen Bonded Clusters Probing the Excited State

Kód výsledku v IS VaVaI

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Výsledek na webu

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DOI - Digital Object Identifier

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Jazyk výsledku

angličtina

Název v původním jazyce

Photodissociation of Molecules in Hydrogen Bonded Clusters Probing the Excited State

Popis výsledku v původním jazyce

We review our recent results on the photodissociation of hydrogen bonded clusters. They are generated in supersonic expansion and subsequently photolyzed. Hydrogen atoms leaving the clusters are detected and the kinetic energy distributions (KEDs) of these outgoing fragments are determined. In the KED spectra, we distinguish three regimes with an increasing kinetic energy: those products which are slowed down by the cluster cage, those which leave it unperturbed and those which gain energy in processesfollowing primary photodissociation. We have analyzed the shapes of the kinetic energy spectra and identified important reaction channels. Our experiments are accompanied and interpreted with theoretical calculations which are based on state-of the-art ab initio methods,

Název v anglickém jazyce

Photodissociation of Molecules in Hydrogen Bonded Clusters Probing the Excited State

Popis výsledku anglicky

We review our recent results on the photodissociation of hydrogen bonded clusters. They are generated in supersonic expansion and subsequently photolyzed. Hydrogen atoms leaving the clusters are detected and the kinetic energy distributions (KEDs) of these outgoing fragments are determined. In the KED spectra, we distinguish three regimes with an increasing kinetic energy: those products which are slowed down by the cluster cage, those which leave it unperturbed and those which gain energy in processesfollowing primary photodissociation. We have analyzed the shapes of the kinetic energy spectra and identified important reaction channels. Our experiments are accompanied and interpreted with theoretical calculations which are based on state-of the-art ab initio methods,

Druh

C - Kapitola v odborné knize

CEP obor

CF - Fyzikální chemie a teoretická chemie

OECD FORD obor

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Projekt

Výsledek vznikl pri realizaci vícero projektů. Více informací v záložce Projekty.

Návaznosti

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Rok uplatnění

2011

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název knihy nebo sborníku

Hydrogen Bonding and Transfer in the Excited State

ISBN

978-0-470-66677-7

Počet stran výsledku

27

Strana od-do

865-891

Počet stran knihy

907

Název nakladatele

John Wiley & Sons Ltd

Místo vydání

Chichester

Kód UT WoS kapitoly

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