The ?3 + ?5 combination band of DCF3: Modeling anharmonic and Coriolis interactions in a three-level system near 1700 cm1

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F12%3A00377500" target="_blank" >RIV/61388955:_____/12:00377500 - isvavai.cz</a>

Výsledek na webu

<a href="http://dx.doi.org/10.1016/j.jms.2012.05.002" target="_blank" >http://dx.doi.org/10.1016/j.jms.2012.05.002</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jms.2012.05.002" target="_blank" >10.1016/j.jms.2012.05.002</a>

Jazyk výsledku

angličtina

Název v původním jazyce

The ?3 + ?5 combination band of DCF3: Modeling anharmonic and Coriolis interactions in a three-level system near 1700 cm1

Popis výsledku v původním jazyce

The degenerate combination level ?3 = ?5 = 1 (1669.09 cm1, E symmetry) was investigated with high-resolution, using a Fourier-transform infrared spectrum recorded in the 1600?1800 cm1 region, at a resolution of 0.0024 cm1. A second spectrum, recorded inthe 900?1100 cm1, at a resolution of 0.0024 cm1, was employed to analyze the ?3 + ?5 ?3 hot band. The studied combination level has to be treated as a part of a polyad including two other dark states: (?3 = 1, ?6 = 2, l6 = 0, +- 2) and (?4 = ?6 = 1). Theimportant anharmonic, Coriolis, and ?-resonance interactions were extrapolated from the previously studied dyads ?5/2?6 and ?4/?3 + ?6. The reproduction thus achieved is quantitative for all the assigned data and provides spectroscopic parameters whichare consistent with those of the system of vibrational levels ?5/2?6.

Název v anglickém jazyce

The ?3 + ?5 combination band of DCF3: Modeling anharmonic and Coriolis interactions in a three-level system near 1700 cm1

Popis výsledku anglicky

The degenerate combination level ?3 = ?5 = 1 (1669.09 cm1, E symmetry) was investigated with high-resolution, using a Fourier-transform infrared spectrum recorded in the 1600?1800 cm1 region, at a resolution of 0.0024 cm1. A second spectrum, recorded inthe 900?1100 cm1, at a resolution of 0.0024 cm1, was employed to analyze the ?3 + ?5 ?3 hot band. The studied combination level has to be treated as a part of a polyad including two other dark states: (?3 = 1, ?6 = 2, l6 = 0, +- 2) and (?4 = ?6 = 1). Theimportant anharmonic, Coriolis, and ?-resonance interactions were extrapolated from the previously studied dyads ?5/2?6 and ?4/?3 + ?6. The reproduction thus achieved is quantitative for all the assigned data and provides spectroscopic parameters whichare consistent with those of the system of vibrational levels ?5/2?6.

Druh

J_x - Nezařazeno - Článek v odborném periodiku (Jimp, Jsc a Jost)

CEP obor

CF - Fyzikální chemie a teoretická chemie

OECD FORD obor

—

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2012

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Journal of Molecular Spectroscopy

ISSN

0022-2852

e-ISSN

—

Svazek periodika

275

Číslo periodika v rámci svazku

276

Stát vydavatele periodika

US - Spojené státy americké

Počet stran výsledku

7

Strana od-do

41-47

Kód UT WoS článku

000306884800009

EID výsledku v databázi Scopus

—