ELECTROCHEMISTRY OF FISCHER AMINOCARBENE COMPLEXES: EFFECTS OF STRUCTURE ON REDOX PROPERTIES, ELECTRON DISTRIBUTION, AND REACTION MECHANISMS

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F14%3A00437065" target="_blank" >RIV/61388955:_____/14:00437065 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/60461373:22310/14:43897436

Výsledek na webu

—

DOI - Digital Object Identifier

—

Jazyk výsledku

angličtina

Název v původním jazyce

ELECTROCHEMISTRY OF FISCHER AMINOCARBENE COMPLEXES: EFFECTS OF STRUCTURE ON REDOX PROPERTIES, ELECTRON DISTRIBUTION, AND REACTION MECHANISMS

Popis výsledku v původním jazyce

Carbene complexes are characterized by the presence of a formal double bond between a central metal atom and a carbene ligand, M= CR2. Generally, these compounds are divided into three groups according to the nature of the metal?carbon bond: nucleophilicSchrock carbenes, where the carbon center has a nucleophilic character, M(? +)=C(? ); and electrophilic Fischer carbenes with the metal?carbon bond polarized in the opposite sense M(? )=C(? +) (the fifteenth annual survey describing their chemistry wasrecently published [1]). The third group includes transition-metal complexes with N-heterocyclic carbene ligands (e.g., the Hoveyda?Grubbs catalyst), in which the multiple character of metal?carbon bond is negligible [2]. This chapter is devoted to carbenes of the Fischer type, that is, to aminocarbene complexes.

Název v anglickém jazyce

ELECTROCHEMISTRY OF FISCHER AMINOCARBENE COMPLEXES: EFFECTS OF STRUCTURE ON REDOX PROPERTIES, ELECTRON DISTRIBUTION, AND REACTION MECHANISMS

Popis výsledku anglicky

Carbene complexes are characterized by the presence of a formal double bond between a central metal atom and a carbene ligand, M= CR2. Generally, these compounds are divided into three groups according to the nature of the metal?carbon bond: nucleophilicSchrock carbenes, where the carbon center has a nucleophilic character, M(? +)=C(? ); and electrophilic Fischer carbenes with the metal?carbon bond polarized in the opposite sense M(? )=C(? +) (the fifteenth annual survey describing their chemistry wasrecently published [1]). The third group includes transition-metal complexes with N-heterocyclic carbene ligands (e.g., the Hoveyda?Grubbs catalyst), in which the multiple character of metal?carbon bond is negligible [2]. This chapter is devoted to carbenes of the Fischer type, that is, to aminocarbene complexes.

Druh

C - Kapitola v odborné knize

CEP obor

CG - Elektrochemie

OECD FORD obor

—

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2014

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název knihy nebo sborníku

Advances in Organometallic Chemistry and Catalysis

ISBN

978-1-118-51014-8

Počet stran výsledku

13

Strana od-do

653-665

Počet stran knihy

736

Název nakladatele

Wiley

Místo vydání

Hoboken

Kód UT WoS kapitoly

—