Recent advances in reactions of alkylbenzenes over novel zeolites: The effects of zeolite structure and morphology

Kód výsledku v IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F14%3A00506968" target="_blank" >RIV/61388955:_____/14:00506968 - isvavai.cz</a>

Nalezeny alternativní kódy

RIV/62243136:_____/14:GACR12CL

Výsledek na webu

<a href="http://hdl.handle.net/11104/0298090" target="_blank" >http://hdl.handle.net/11104/0298090</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1080/01614940.2014.946846" target="_blank" >10.1080/01614940.2014.946846</a>

Jazyk výsledku

angličtina

Název v původním jazyce

Recent advances in reactions of alkylbenzenes over novel zeolites: The effects of zeolite structure and morphology

Popis výsledku v původním jazyce

Alkylbenzenes form an important segment of petrochemical industry for the manufacture of widely used commodities and specialty products. Since the last review on this topic (8), numerous new zeolite-based catalysts have been synthesized, characterized and evaluated in various transformations of aromatic hydrocarbons. This comprehensive review covers major reactions of mono-, di-, and tri-alkylbenzenes such as disproportionation, alkylation, transalkylation, isomerization, etc., over different zeolite-based acid catalysts. During the last decade, significant progress was made in the synthesis and structure determination of novel zeolites, mesoporous single crystals, hierarchic zeolites and two-dimensional zeolites. These developments have enhanced the understanding of the role of zeolites (effects of structural type, morphology, acid sites, accessibility of acid sites, shape selectivity factors) in transformations of aromatics. In this review, the emphasis is on the influence of the type of acid sites, zeolite topology, and reaction conditions on the activity, selectivity and pathways of these reactions. Thermodynamics and reaction kinetics of transformations of aromatic hydrocarbons are also discussed. This article covers mostly literature published during the period of 2002-2013.

Název v anglickém jazyce

Recent advances in reactions of alkylbenzenes over novel zeolites: The effects of zeolite structure and morphology

Popis výsledku anglicky

Alkylbenzenes form an important segment of petrochemical industry for the manufacture of widely used commodities and specialty products. Since the last review on this topic (8), numerous new zeolite-based catalysts have been synthesized, characterized and evaluated in various transformations of aromatic hydrocarbons. This comprehensive review covers major reactions of mono-, di-, and tri-alkylbenzenes such as disproportionation, alkylation, transalkylation, isomerization, etc., over different zeolite-based acid catalysts. During the last decade, significant progress was made in the synthesis and structure determination of novel zeolites, mesoporous single crystals, hierarchic zeolites and two-dimensional zeolites. These developments have enhanced the understanding of the role of zeolites (effects of structural type, morphology, acid sites, accessibility of acid sites, shape selectivity factors) in transformations of aromatics. In this review, the emphasis is on the influence of the type of acid sites, zeolite topology, and reaction conditions on the activity, selectivity and pathways of these reactions. Thermodynamics and reaction kinetics of transformations of aromatic hydrocarbons are also discussed. This article covers mostly literature published during the period of 2002-2013.

Druh

J_imp - Článek v periodiku v databázi Web of Science

CEP obor

—

OECD FORD obor

10403 - Physical chemistry

Projekt

—

Návaznosti

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Rok uplatnění

2014

Kód důvěrnosti údajů

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Název periodika

Catalysis Reviews-Science and Engineering

ISSN

0161-4940

e-ISSN

—

Svazek periodika

56

Číslo periodika v rámci svazku

4

Stát vydavatele periodika

NL - Nizozemsko

Počet stran výsledku

70

Strana od-do

333-402

Kód UT WoS článku

000342284800001

EID výsledku v databázi Scopus

2-s2.0-84908477549